An X-ray crystallorgraphic study of the reagent Ph 3 PCl 2 ; not charge-transfer, R 3 P–Cl–Cl, trigonal bipyramidal or [R 3 PCl]Cl but an unusual dinuclear ionic species, [Ph 3 PCl + ⋯Cl – ⋯ + CIPPH 3 ]Cl containing long Cl–Cl contacts

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Published in:Chemical communications (Cambridge, England) England), 1996 (22), p.2521-2522
Main Authors: Godfrey, Stephen M., McAuliffe, Charles A., Pritchard, Robin G., Sheffield, Joanne M.
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Language:English
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title An X-ray crystallorgraphic study of the reagent Ph 3 PCl 2 ; not charge-transfer, R 3 P–Cl–Cl, trigonal bipyramidal or [R 3 PCl]Cl but an unusual dinuclear ionic species, [Ph 3 PCl + ⋯Cl – ⋯ + CIPPH 3 ]Cl containing long Cl–Cl contacts
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