Unveiling anion-induced folding in tripodal imidazolium receptors by ion-mobility mass spectrometry

The anion-induced folding of tripodal imidazolium receptors has been investigated by NMR spectroscopy, electrospray ionization ion mobility mass spectrometry and DFT calculations. Such folding can be switched by anion release upon collision induced dissociation. The anion-induced folding of tripodal...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2021-09, Vol.57 (69), p.8616-8619
Main Authors: Vicent, Cristian, Valls, Adriana, Escorihuela, Jorge, Altava, Belén, Luis, Santiago
Format: Article
Language:English
Subjects:
Anions
Folding
Ionic mobility
Ions
Mass spectrometry
NMR spectroscopy
Receptors
Scientific imaging
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Summary:The anion-induced folding of tripodal imidazolium receptors has been investigated by NMR spectroscopy, electrospray ionization ion mobility mass spectrometry and DFT calculations. Such folding can be switched by anion release upon collision induced dissociation. The anion-induced folding of tripodal imidazolium receptors is unveiled by Ion mobility mass spectrometry and DFT calculations.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc02818a