Sustainable and cost-effective ternary electrolyte Et 3 NHCl-AlCl 3 -Mg(DEP) 2 for high-performance rechargeable magnesium batteries

• Published in: Physical chemistry chemical physics : PCCP 2022-01, Vol.24 (3), p.1840-1848
• Main Authors: Prabhakar, Seggem, Chavan, Santosh N, Basak, Pratyay, Jetti, Vatsala Rani
• Format: Article
• Language: English
• ISSN: 1463-9076; 1463-9084
• DOI: 10.1039/D1CP04794A

Cost-effective and sustainable battery materials for large-scale batteries are the need of the hour to garner renewable energy with high-performance metal battery technologies. Here, we report the high-performance and long cycle life electrolyte prepared from low-cost triethylamine hydrochloride (Et NHCl) and aluminum chloride (AlCl ) termed as (TA) with different concentrations of magnesium diethylphosphate (Mg(DEP) ) salt. The optimized ratio of the 0.1 M Mg(DEP) electrolyte has shown a high ionic conductivity of 4.5 × 10 S cm at ambient temperature and good anodic stability of 2.41 V Mg/Mg . The dissolution/deposition of magnesium (Mg) on a Pt working electrode was systematically analyzed in this electrolyte. Cyclic voltammetry (CV) of the Mg-graphite battery was used to probe the intercalation/de-intercalation of Mg-AlCl ions into/from the graphite layer structure. This was confirmed by various analytical techniques, such as energy dispersive X-ray spectroscopy, X-ray diffraction technique and X-ray photoemission spectroscopy. Notably, during the galvanostatic study analysis, the assembled Mg cell delivered a high discharge capacity of 115 mA h g at a high C/10 rate, with more than 180 cycles at >80% coulombic efficiency. This electrolyte will be helpful in grid-scale power storage systems in future generations.