The influence of the Sc 3+ dopant on the transmittance of (Y, Er) 3 Al 5 O 12 ceramics

High erbium content yttrium aluminum garnet (Er:YAG) and yttrium scandium aluminum garnet (Er:YSAG) ceramics have been fabricated from Er:YAG and Er:YSAG powders, respectively. The powders have been synthesized via a reverse precipitation technique, processed by uniaxial pressing followed by cold is...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.50 (40), p.14252-14256
Main Authors: Dobretsova, Elena, Zhmykhov, Vadim, Kuznetsov, Sergey, Chikulina, Irina, Nikova, Marina, Tarala, Vitaly, Vakalov, Dmitry, Khmelnitsky, Roman, Pynenkov, Alexander, Nishchev, Konstantin, Tsvetkov, Vladimir
Format: Article
Language:English
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Summary:High erbium content yttrium aluminum garnet (Er:YAG) and yttrium scandium aluminum garnet (Er:YSAG) ceramics have been fabricated from Er:YAG and Er:YSAG powders, respectively. The powders have been synthesized via a reverse precipitation technique, processed by uniaxial pressing followed by cold isostatic pressing, and sintered in a vacuum. TEOS (tetraethoxysilane) was used as a sintering additive. After vacuum sintering, all of the samples were processed by annealing in air to increase the transmittance and polished on both sides. The influence of the Sc 3+ content and the synthesis conditions on the microstructure and optical transparency of the Er:YAG and Er:YSAG ceramics have been investigated in detail. It has been found that changing Al 3+ for the bigger Sc 3+ ion leads to the transmittance increasing to up to 60% at a wavelength of about 1500 nm.
ISSN:1477-9226
1477-9234
DOI:10.1039/D1DT02419A