Light-enabled alkenylation of iodocarboranes with unactivated alkenes

The synthesis of alkenylated- o -carboranes via photoalkenylation of iodocarboranes with unactivated alkenes has been achieved. This strategy features a transition metal-free protocol, a light-promoted reaction under mild reaction conditions, broad substrate scope and good functional group tolerance...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2021-12, Vol.51 (1), p.14-11
Main Authors: Ni, Hangcheng, Lu, Zhenpin, Xie, Zuowei
Format: Article
Language:English
Subjects:
Alkenes
Functional groups
Substrates
Transition metals
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Summary:The synthesis of alkenylated- o -carboranes via photoalkenylation of iodocarboranes with unactivated alkenes has been achieved. This strategy features a transition metal-free protocol, a light-promoted reaction under mild reaction conditions, broad substrate scope and good functional group tolerance. Control experiments suggest that the reaction may involve the cage C-centered radical species. Transition metal-free photoalkenylation of iodocarboranes with unactivated alkenes has been achieved for the facile synthesis of alkenylated- o -carboranes with broad substrate scope and good functional group tolerance under mild reaction conditions.
ISSN:1477-9226
1477-9234
DOI:10.1039/d1dt03726a