Probing the local activity of CO 2 reduction on gold gas diffusion electrodes: effect of the catalyst loading and CO 2 pressure

• Published in: Chemical science (Cambridge) 2021-12, Vol.12 (47), p.15682-15690
• Main Authors: Monteiro, Mariana C O, Dieckhöfer, Stefan, Bobrowski, Tim, Quast, Thomas, Pavesi, Davide, Koper, Marc T M, Schuhmann, Wolfgang
• Format: Article
• Language: English
• ISSN: 2041-6520; 2041-6539
• DOI: 10.1039/d1sc05519d

Large scale CO electrolysis can be achieved using gas diffusion electrodes (GDEs), and is an essential step towards broader implementation of carbon capture and utilization strategies. Different variables are known to affect the performance of GDEs. Especially regarding the catalyst loading, there are diverging trends reported in terms of activity and selectivity, for CO reduction to CO. We have used shear-force based Au nanoelectrode positioning and scanning electrochemical microscopy (SECM) in the surface-generation tip collection mode to evaluate the activity of Au GDEs for CO reduction as a function of catalyst loading and CO back pressure. Using a Au nanoelectrode, we have locally measured the amount of CO produced along a catalyst loading gradient under conditions. We observed that an optimum local loading of catalyst is necessary to achieve high activities. However, this optimum is directly dependent on the CO back pressure. Our work does not only present a tool to evaluate the activity of GDEs locally, it also allows drawing a more precise picture regarding the effect of catalyst loading and CO back pressure on their performance.