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Ancillary ligand-regulated Ti( iv )-based metallocalixarene coordination cages for photocatalytic H 2 evolution
High-valence Ti( iv )-based metallocalixarene coordination cages that are linked by oriented ancillary ligands are unknown so far. Herein, the first family of tunable calixarene-based coordination cages of Ti( iv ) with a framework formula [Ti 12 (O i Pr) 12 (TBC[4]) 6 L 6 ] have been assembled from...
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| Published in: | Chemical communications (Cambridge, England) England), 2022-08, Vol.58 (64), p.9034-9037 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c161t-28936ed4484a999e0774aaeec02871f2249748147e39327d3c506b4aebfc1f1a3 |
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| cites | cdi_FETCH-LOGICAL-c161t-28936ed4484a999e0774aaeec02871f2249748147e39327d3c506b4aebfc1f1a3 |
| container_end_page | 9037 |
| container_issue | 64 |
| container_start_page | 9034 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 58 |
| creator | Tian, Yi-Qi Cui, Yun-Shu Zhu, Jia-Hui Xu, Cong-Qiao Yi, Xiao-Yi Li, Jun Liu, Chao |
| description | High-valence Ti(
iv
)-based metallocalixarene coordination cages that are linked by oriented ancillary ligands are unknown so far. Herein, the first family of tunable calixarene-based coordination cages of Ti(
iv
) with a framework formula [Ti
12
(O
i
Pr)
12
(TBC[4])
6
L
6
] have been assembled from six {Ti
2
(O
i
Pr)
2
(TBC[4])}
2+
nodes and six pyridinedicarboxylic ligands. Furthermore, the {Ti12L6} cage showed strong photocatalytic H
2
evolution activity, and DFT studies were performed to explore its electronic structure. |
| doi_str_mv | 10.1039/D2CC03131K |
| format | article |
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iv
)-based metallocalixarene coordination cages that are linked by oriented ancillary ligands are unknown so far. Herein, the first family of tunable calixarene-based coordination cages of Ti(
iv
) with a framework formula [Ti
12
(O
i
Pr)
12
(TBC[4])
6
L
6
] have been assembled from six {Ti
2
(O
i
Pr)
2
(TBC[4])}
2+
nodes and six pyridinedicarboxylic ligands. Furthermore, the {Ti12L6} cage showed strong photocatalytic H
2
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iv
)-based metallocalixarene coordination cages that are linked by oriented ancillary ligands are unknown so far. Herein, the first family of tunable calixarene-based coordination cages of Ti(
iv
) with a framework formula [Ti
12
(O
i
Pr)
12
(TBC[4])
6
L
6
] have been assembled from six {Ti
2
(O
i
Pr)
2
(TBC[4])}
2+
nodes and six pyridinedicarboxylic ligands. Furthermore, the {Ti12L6} cage showed strong photocatalytic H
2
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iv
)-based metallocalixarene coordination cages that are linked by oriented ancillary ligands are unknown so far. Herein, the first family of tunable calixarene-based coordination cages of Ti(
iv
) with a framework formula [Ti
12
(O
i
Pr)
12
(TBC[4])
6
L
6
] have been assembled from six {Ti
2
(O
i
Pr)
2
(TBC[4])}
2+
nodes and six pyridinedicarboxylic ligands. Furthermore, the {Ti12L6} cage showed strong photocatalytic H
2
evolution activity, and DFT studies were performed to explore its electronic structure.</abstract><doi>10.1039/D2CC03131K</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-5482-9496</orcidid><orcidid>https://orcid.org/0000-0003-4593-3288</orcidid><orcidid>https://orcid.org/0000-0002-2289-3095</orcidid><orcidid>https://orcid.org/0000-0002-8456-3980</orcidid></addata></record> |
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| ispartof | Chemical communications (Cambridge, England), 2022-08, Vol.58 (64), p.9034-9037 |
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| language | eng |
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| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| title | Ancillary ligand-regulated Ti( iv )-based metallocalixarene coordination cages for photocatalytic H 2 evolution |
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