SmI 2 -mediated intermolecular addition–elimination of piperidine and pyrrolidine N -α-radicals with arylacetylene sulfones

An efficient approach to access α-arylacetylene-substituted pyrrolidine and piperidine derivatives has been developed through a samarium diiodide-mediated addition–elimination process of pyrrolidine and piperidine N -α-radicals with arylacetylene sulfones.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2022-09, Vol.58 (77), p.10841-10844
Main Authors: Liu, Chang-Hong, Guo, Jia-Ming, Li, Xin, Sun, Jian-Ting, Wei, Bang-Guo, Si, Chang-Mei
Format: Article
Language:English
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Description
Summary:An efficient approach to access α-arylacetylene-substituted pyrrolidine and piperidine derivatives has been developed through a samarium diiodide-mediated addition–elimination process of pyrrolidine and piperidine N -α-radicals with arylacetylene sulfones.
ISSN:1359-7345
1364-548X
DOI:10.1039/D2CC03984B