Insights into the role of molar ratio and added water in the properties of choline chloride and urea-based eutectic mixtures and their cellulose swelling capacity

• Published in: Physical chemistry chemical physics : PCCP 2022-11, Vol.24 (46), p.2869-2862
• Main Authors: Sirviö, Juho Antti, Haataja, Riikka, Kantola, Anu M, Suopajärvi, Terhi, Liimatainen, Henrikki
• Format: Article
• Language: English
• Subjects: Basicity; Cellulose fibers; Chemical equilibrium; Chloride; Chlorides; Choline; Diameters; Eutectic composition; Hydrogen bonds; Lignocellulose; Magnetic methods; Mixtures; Moisture content; Molecular clusters; Solvents; Swelling; Ureas; Viscosity
• ISSN: 1463-9076; 1463-9084
• DOI: 10.1039/d2cp04119g

Eutectic mixtures and deep eutectic solvents (DESs) are promising green media for the pre-treatment of lignocellulose materials. They can be harnessed for the swelling of cellulose and further facilitate cellulose hydrolysis, derivatization, and production of cellulose-based (nano) materials. Several studies indicated that water can take part in the formation of the nanostructure of DES; however, it is still unclear how additional water influences many important properties and functioning of DES, especially when the molar ratio of compounds differs from the eutectic point composition. Here, viscosity, pH, conductivity, solvatochromic and solvatomagnetic solvent parameters, and fiber swelling capacity of choline chloride and urea mixtures demonstrating different molar ratios were investigated in the presence and absence of added water. The participation of water in the formation of molecular clusters with choline chloride and urea was indicated by viscosity, pH, and conductivity measurements. Hydrogen bond acceptor values of aqueous mixtures increased as a function of water content, and the results obtained using both methods were in line, indicating their suitability for the determination of hydrogen bond acidity of aqueous choline chloride-urea mixtures. However, hydrogen bond basicity determined by solvatochromic and magnetic methods exhibited almost opposite trends. The close investigation of the chemical shift of solvatomagnetic probes indicated that the chemical environment of the choline chloride-urea (1 : 2) mixture remained constant until the water content of 30 wt% was in line with previous molecular simulations. When cellulose fibers were treated with mixtures under mixing, the non-ideality of the choline chloride-urea mixture and the absence of water were found to be advantageous; however, aqueous mixtures efficiently increased the diameters of cellulose fibers in the absence of mixing, and water-containing mixtures appeared to be appealing systems for cellulose pretreatments. An aqueous eutectic mixture of choline chloride, urea, water at different molar ratios were characterized and experimental results of the formation of molecular clusters and swelling of cellulose fibers was demonstrated.