Evaluating the efficacy of nanosized CuZnAl and CuZnZr mixed oxides for electrocatalytic CO 2 reduction

• Published in: Dalton transactions : an international journal of inorganic chemistry 2023-04, Vol.52 (16), p.5155-5168
• Main Authors: Mostafa, Mohamed Mokhtar M, Li, Yining, Halawani, Wael, Narasimharao, Katabathini, Abdel Salam, Mohamed, Alshehri, Abdulmohsen A, Khdary, Nezar H, Al-Faifi, Sulaiman, Gu, Lin, Dutta Chowdhury, Abhishek
• Format: Article
• Language: English
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d2dt04111a

The increased awareness of carbon management has prompted the scientific community towards delivering sustainable catalytic technologies, preferably from CO . Copper-based multifunctional catalysts are the most frequently used for thermal hydrogenation and electrocatalytic reduction of CO (CO R) processes. To improve the understanding and efficacy of these materials for the CO R reaction, Cu-Zn oxides combined with Al O and ZrO were synthesized by the coprecipitation method and annealed at 500 °C, 600 °C, and 700 °C ( , Cu/ZnO/Al O - and Cu/ZnO/ZrO systems- , where is the annealing temperature) to tune their multi-functionality. We demonstrate that the composition of Cu-Zn oxides and pretreatment temperature impact the electrocatalytic CO R performance, where CuZnZr-600 and CuZnAl-700 materials are superior. Different characterization tools were employed to rationalize the results described in this work, which could provide a way to design an efficient catalytic system for the CO R process.