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Tuning magnetic properties by crystal engineering in a family of coordination polymers based on Ni() sulphates
A new family of hybrid organic-inorganic layered materials based on nickel sulfates was synthesized using a simple, solvent-free synthesis approach using 1,2-phenylenediamine (OPD), 1,3-phenylenediamine (MPD), and 1,4-phenylenediamine (PPD) as organic templates and ligands. Diamines act as structure...
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| Published in: | New journal of chemistry 2022-08, Vol.46 (31), p.14786-14792 |
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| Main Authors: | , , , , , |
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| cites | cdi_FETCH-LOGICAL-c281t-992a97d95d4ea1ed061e2b2a57eb4aa72d5dfb64cb868137e9c0a6a2e11271213 |
| container_end_page | 14792 |
| container_issue | 31 |
| container_start_page | 14786 |
| container_title | New journal of chemistry |
| container_volume | 46 |
| creator | González Guillén, Anabel B Konieczny, Piotr Luberda-Durna, Katarzyna Oszajca, Marcin Kozie, Marcin asocha, Wies aw |
| description | A new family of hybrid organic-inorganic layered materials based on nickel sulfates was synthesized using a simple, solvent-free synthesis approach using 1,2-phenylenediamine (OPD), 1,3-phenylenediamine (MPD), and 1,4-phenylenediamine (PPD) as organic templates and ligands. Diamines act as structure-directing agents to obtain 1D [Ni(OPD)
2
SO
4
] (
1
), 2D [Ni(MPD)
2
SO
4
] (
2
) and 3D [Ni(PPD)SO
4
] (
3
) frameworks. The crystal structures of
1-3
were determined using data from X-ray powder diffraction (XRPD) measurements and represent
I
2/
a
,
Cc
, and
Cmcm
space groups, respectively. The compounds display different dimensionalities of the frameworks; however, the magnetic studies reveal transitions to 3D magnetic long-range ordered phases in all three cases below 23 K (
1
), 25 K (
2
) and 25 K (
3
). The observed ordering in all compounds is a consequence of significant interchain (
1
) and intralayer (
2
and
3
) interactions which lead to considerable spinspin correlations, which are strong enough to couple the adjacent layers. In addition, in all three compounds, there is a competition between ferromagnetic and antiferromagnetic interactions in which the latter ones successively get stronger with the substitution of dipolar couplings by superexchange ones.
A new family of hybrid organic-inorganic layered materials based on nickel sulfates was synthesized using a one-pot, solvent-free synthetic approach using 1,2-phenylenediamine (OPD), 1,3-phenylenediamine (MPD) and 1,4-phenylenediamine (PPD). |
| doi_str_mv | 10.1039/d2nj01188c |
| format | article |
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2
SO
4
] (
1
), 2D [Ni(MPD)
2
SO
4
] (
2
) and 3D [Ni(PPD)SO
4
] (
3
) frameworks. The crystal structures of
1-3
were determined using data from X-ray powder diffraction (XRPD) measurements and represent
I
2/
a
,
Cc
, and
Cmcm
space groups, respectively. The compounds display different dimensionalities of the frameworks; however, the magnetic studies reveal transitions to 3D magnetic long-range ordered phases in all three cases below 23 K (
1
), 25 K (
2
) and 25 K (
3
). The observed ordering in all compounds is a consequence of significant interchain (
1
) and intralayer (
2
and
3
) interactions which lead to considerable spinspin correlations, which are strong enough to couple the adjacent layers. In addition, in all three compounds, there is a competition between ferromagnetic and antiferromagnetic interactions in which the latter ones successively get stronger with the substitution of dipolar couplings by superexchange ones.
A new family of hybrid organic-inorganic layered materials based on nickel sulfates was synthesized using a one-pot, solvent-free synthetic approach using 1,2-phenylenediamine (OPD), 1,3-phenylenediamine (MPD) and 1,4-phenylenediamine (PPD).</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d2nj01188c</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Antiferromagnetism ; Coordination polymers ; Couplings ; Crystal structure ; Diamines ; Ferromagnetism ; Layered materials ; Magnetic properties ; Nickel sulfate ; Phenylenediamine ; X ray powder diffraction</subject><ispartof>New journal of chemistry, 2022-08, Vol.46 (31), p.14786-14792</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-992a97d95d4ea1ed061e2b2a57eb4aa72d5dfb64cb868137e9c0a6a2e11271213</citedby><cites>FETCH-LOGICAL-c281t-992a97d95d4ea1ed061e2b2a57eb4aa72d5dfb64cb868137e9c0a6a2e11271213</cites><orcidid>0000-0001-8769-8023 ; 0000-0002-5185-3885 ; 0000-0001-7083-1860 ; 0000-0003-2309-4540 ; 0000-0002-0024-9557 ; 0000-0002-9606-7642</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>González Guillén, Anabel B</creatorcontrib><creatorcontrib>Konieczny, Piotr</creatorcontrib><creatorcontrib>Luberda-Durna, Katarzyna</creatorcontrib><creatorcontrib>Oszajca, Marcin</creatorcontrib><creatorcontrib>Kozie, Marcin</creatorcontrib><creatorcontrib>asocha, Wies aw</creatorcontrib><title>Tuning magnetic properties by crystal engineering in a family of coordination polymers based on Ni() sulphates</title><title>New journal of chemistry</title><description>A new family of hybrid organic-inorganic layered materials based on nickel sulfates was synthesized using a simple, solvent-free synthesis approach using 1,2-phenylenediamine (OPD), 1,3-phenylenediamine (MPD), and 1,4-phenylenediamine (PPD) as organic templates and ligands. Diamines act as structure-directing agents to obtain 1D [Ni(OPD)
2
SO
4
] (
1
), 2D [Ni(MPD)
2
SO
4
] (
2
) and 3D [Ni(PPD)SO
4
] (
3
) frameworks. The crystal structures of
1-3
were determined using data from X-ray powder diffraction (XRPD) measurements and represent
I
2/
a
,
Cc
, and
Cmcm
space groups, respectively. The compounds display different dimensionalities of the frameworks; however, the magnetic studies reveal transitions to 3D magnetic long-range ordered phases in all three cases below 23 K (
1
), 25 K (
2
) and 25 K (
3
). The observed ordering in all compounds is a consequence of significant interchain (
1
) and intralayer (
2
and
3
) interactions which lead to considerable spinspin correlations, which are strong enough to couple the adjacent layers. In addition, in all three compounds, there is a competition between ferromagnetic and antiferromagnetic interactions in which the latter ones successively get stronger with the substitution of dipolar couplings by superexchange ones.
A new family of hybrid organic-inorganic layered materials based on nickel sulfates was synthesized using a one-pot, solvent-free synthetic approach using 1,2-phenylenediamine (OPD), 1,3-phenylenediamine (MPD) and 1,4-phenylenediamine (PPD).</description><subject>Antiferromagnetism</subject><subject>Coordination polymers</subject><subject>Couplings</subject><subject>Crystal structure</subject><subject>Diamines</subject><subject>Ferromagnetism</subject><subject>Layered materials</subject><subject>Magnetic properties</subject><subject>Nickel sulfate</subject><subject>Phenylenediamine</subject><subject>X ray powder diffraction</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpFkE1LxDAQQIMouK5evAsBLypUM2mbNkdZv1nWy3ouaTpds7RpTdpD_71ZVxQGZhjezDCPkHNgt8BieVdxu2UAea4PyAxiISPJBRyGGpIkYmkijsmJ91sWoEzAjNj1aI3d0FZtLA5G0951PbrBoKflRLWb_KAainZjLKLbocZSRWvVmmaiXU1117nKWDWYztK-a6YWXZhVHisaOitzdU392PSfakB_So5q1Xg8-81z8vH0uF68RMv359fF_TLSPIchkpIrmVUyrRJUgBUTgLzkKs2wTJTKeJVWdSkSXeYihzhDqZkSiiMAz4BDPCeX-73hna8R_VBsu9HZcLLgQsoQeSYCdbOntOu8d1gXvTOtclMBrNj5LB746u3H5yLAF3vYef3H_fuOvwFLAnNS</recordid><startdate>20220808</startdate><enddate>20220808</enddate><creator>González Guillén, Anabel B</creator><creator>Konieczny, Piotr</creator><creator>Luberda-Durna, Katarzyna</creator><creator>Oszajca, Marcin</creator><creator>Kozie, Marcin</creator><creator>asocha, Wies aw</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0001-8769-8023</orcidid><orcidid>https://orcid.org/0000-0002-5185-3885</orcidid><orcidid>https://orcid.org/0000-0001-7083-1860</orcidid><orcidid>https://orcid.org/0000-0003-2309-4540</orcidid><orcidid>https://orcid.org/0000-0002-0024-9557</orcidid><orcidid>https://orcid.org/0000-0002-9606-7642</orcidid></search><sort><creationdate>20220808</creationdate><title>Tuning magnetic properties by crystal engineering in a family of coordination polymers based on Ni() sulphates</title><author>González Guillén, Anabel B ; Konieczny, Piotr ; Luberda-Durna, Katarzyna ; Oszajca, Marcin ; Kozie, Marcin ; asocha, Wies aw</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-992a97d95d4ea1ed061e2b2a57eb4aa72d5dfb64cb868137e9c0a6a2e11271213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Antiferromagnetism</topic><topic>Coordination polymers</topic><topic>Couplings</topic><topic>Crystal structure</topic><topic>Diamines</topic><topic>Ferromagnetism</topic><topic>Layered materials</topic><topic>Magnetic properties</topic><topic>Nickel sulfate</topic><topic>Phenylenediamine</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>González Guillén, Anabel B</creatorcontrib><creatorcontrib>Konieczny, Piotr</creatorcontrib><creatorcontrib>Luberda-Durna, Katarzyna</creatorcontrib><creatorcontrib>Oszajca, Marcin</creatorcontrib><creatorcontrib>Kozie, Marcin</creatorcontrib><creatorcontrib>asocha, Wies aw</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>González Guillén, Anabel B</au><au>Konieczny, Piotr</au><au>Luberda-Durna, Katarzyna</au><au>Oszajca, Marcin</au><au>Kozie, Marcin</au><au>asocha, Wies aw</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tuning magnetic properties by crystal engineering in a family of coordination polymers based on Ni() sulphates</atitle><jtitle>New journal of chemistry</jtitle><date>2022-08-08</date><risdate>2022</risdate><volume>46</volume><issue>31</issue><spage>14786</spage><epage>14792</epage><pages>14786-14792</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>A new family of hybrid organic-inorganic layered materials based on nickel sulfates was synthesized using a simple, solvent-free synthesis approach using 1,2-phenylenediamine (OPD), 1,3-phenylenediamine (MPD), and 1,4-phenylenediamine (PPD) as organic templates and ligands. Diamines act as structure-directing agents to obtain 1D [Ni(OPD)
2
SO
4
] (
1
), 2D [Ni(MPD)
2
SO
4
] (
2
) and 3D [Ni(PPD)SO
4
] (
3
) frameworks. The crystal structures of
1-3
were determined using data from X-ray powder diffraction (XRPD) measurements and represent
I
2/
a
,
Cc
, and
Cmcm
space groups, respectively. The compounds display different dimensionalities of the frameworks; however, the magnetic studies reveal transitions to 3D magnetic long-range ordered phases in all three cases below 23 K (
1
), 25 K (
2
) and 25 K (
3
). The observed ordering in all compounds is a consequence of significant interchain (
1
) and intralayer (
2
and
3
) interactions which lead to considerable spinspin correlations, which are strong enough to couple the adjacent layers. In addition, in all three compounds, there is a competition between ferromagnetic and antiferromagnetic interactions in which the latter ones successively get stronger with the substitution of dipolar couplings by superexchange ones.
A new family of hybrid organic-inorganic layered materials based on nickel sulfates was synthesized using a one-pot, solvent-free synthetic approach using 1,2-phenylenediamine (OPD), 1,3-phenylenediamine (MPD) and 1,4-phenylenediamine (PPD).</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2nj01188c</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-8769-8023</orcidid><orcidid>https://orcid.org/0000-0002-5185-3885</orcidid><orcidid>https://orcid.org/0000-0001-7083-1860</orcidid><orcidid>https://orcid.org/0000-0003-2309-4540</orcidid><orcidid>https://orcid.org/0000-0002-0024-9557</orcidid><orcidid>https://orcid.org/0000-0002-9606-7642</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | New journal of chemistry, 2022-08, Vol.46 (31), p.14786-14792 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D2NJ01188C |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Antiferromagnetism Coordination polymers Couplings Crystal structure Diamines Ferromagnetism Layered materials Magnetic properties Nickel sulfate Phenylenediamine X ray powder diffraction |
| title | Tuning magnetic properties by crystal engineering in a family of coordination polymers based on Ni() sulphates |
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