Electrochemical atomic force microscopy of two-dimensional trinuclear ruthenium clusters molecular assembly and dynamics under redox state control

Mixed-valence ruthenium trinuclear clusters containing dichloroacetates were synthesized, and the self-assembly of a single molecular adlayer composed of these clusters on a graphite surface was investigated by atomic force microscopy (AFM). AFM clearly revealed the dynamics of two-dimensional (2D)...

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Published in:Nanoscale 2022-06, Vol.14 (25), p.8929-8933
Main Authors: Yoshimoto, Soichiro, Kato, Jinnosuke, Sakamoto, Hiroki, Minamoto, Hironori, Daicho, Keita, Takamura, Kazuki, Shimomoto, Naoki, Abe, Masaaki
Format: Article
Language:English
Subjects:
Atomic force microscopy
Clusters
Coordination compounds
Dynamic structural analysis
Molecular structure
Ruthenium
Self-assembly
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container_title Nanoscale
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creator Yoshimoto, Soichiro
Kato, Jinnosuke
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description Mixed-valence ruthenium trinuclear clusters containing dichloroacetates were synthesized, and the self-assembly of a single molecular adlayer composed of these clusters on a graphite surface was investigated by atomic force microscopy (AFM). AFM clearly revealed the dynamics of two-dimensional (2D) structure formation as well as the molecular characteristics of the adlayers at different electrochemical interfaces. The results verified that the design of metal complexes is important not only for redox chemistry but also for molecular assembly and nanoarchitecture construction. Mixed-valence ruthenium trinuclear clusters containing dichloroacetates were synthesized, and the self-assembly of a single molecular adlayer composed of these clusters on a graphite surface was investigated by atomic force microscopy.
doi_str_mv 10.1039/d2nr01666d
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Atomic force microscopy
Clusters
Coordination compounds
Dynamic structural analysis
Molecular structure
Ruthenium
Self-assembly
title Electrochemical atomic force microscopy of two-dimensional trinuclear ruthenium clusters molecular assembly and dynamics under redox state control
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