Structure and assembly of a hexanuclear AuNi bimetallic nanocluster

An Au 4 Ni 2 nanocluster containing a square-planar [-PPh 2 -Au-S-Au-] 2 ring and two nickel-pincer arms is reported here. Abundant intra- and inter-cluster noncovalent interactions promote the assembly of the nanocluster into a porous framework material. The assembly-dependent unique solubility and...

Full description

Saved in:
Bibliographic Details
Published in:Nanoscale 2022-12, Vol.15 (1), p.19-113
Main Authors: Tao, Cheng-Bo, Fan, Ji-Qiang, Fei, Wenwen, Zhao, Yan, Li, Man-Bo
Format: Article
Language:English
Subjects:
Assembly
Bimetals
Nanoclusters
Photoluminescence
Porous materials
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:An Au 4 Ni 2 nanocluster containing a square-planar [-PPh 2 -Au-S-Au-] 2 ring and two nickel-pincer arms is reported here. Abundant intra- and inter-cluster noncovalent interactions promote the assembly of the nanocluster into a porous framework material. The assembly-dependent unique solubility and photoluminescence were also investigated. An Au 4 Ni 2 nanocluster containing a square-planar [PPh 2 -Au-S-Au] 2 ring and two nickel-pincer arms was found to be assembled by noncovalent interactions. The assembly-dependent properties that are distinct from the octahedral M 6 clusters were shown.
ISSN:2040-3364
2040-3372
DOI:10.1039/d2nr05225c