Selective electrochemical CO 2 conversion with a hybrid polyoxometalate

A multi-component coordination compound, in which ruthenium antenna complexes are connected to a polyoxotungstate core is presented. This hybrid cluster effectively promotes the electrochemical conversion of CO 2 to C1 feedstocks, the selectivity of which can be controlled by the acidity of the medi...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2023-09, Vol.59 (72), p.10801-10804
Main Authors: Kuramochi, Satoshi, Cameron, Jamie M., Fukui, Tomoya, Jones, Kieran D., Argent, Stephen P., Kusaka, Shinpei, Shiraishi, Ryo, Tamaki, Yusuke, Yatsu, Taiki, Shiga, Takuya, Ishitani, Osamu, Oshio, Hiroki, Newton, Graham N.
Format: Article
Language:English
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Summary:A multi-component coordination compound, in which ruthenium antenna complexes are connected to a polyoxotungstate core is presented. This hybrid cluster effectively promotes the electrochemical conversion of CO 2 to C1 feedstocks, the selectivity of which can be controlled by the acidity of the media.
ISSN:1359-7345
1364-548X
DOI:10.1039/D3CC02138F