Synthesis of spiropyrans and arylquinones via Ru( ii )-catalyzed condition-controlled coupling of 3-aryl-2 H -benzoxazinones with benzoquinones

Ru( ii )-catalyzed condition-controlled divergent coupling between 3-aryl-2 H -benzoxazin-2-ones and benzoquinones has been realized under operationally simple conditions, affording a series of structurally stable spiropyrans and valuable arylquinones. The potential of this method is also demonstrat...

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Published in:Chemical communications (Cambridge, England) England), 2023-09, Vol.59 (78), p.11704-11707
Main Authors: Zhang, Mengying, He, Yuhao, Li, Song, Geng, Yuehua, Liu, Xiangyang, Yang, Xifa
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Language:English
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cited_by cdi_FETCH-LOGICAL-c76C-d66c66da750eaf5ba2179c27e88c11148e6c10539d7ab71e42a35eed79f06b013
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container_issue 78
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container_title Chemical communications (Cambridge, England)
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creator Zhang, Mengying
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description Ru( ii )-catalyzed condition-controlled divergent coupling between 3-aryl-2 H -benzoxazin-2-ones and benzoquinones has been realized under operationally simple conditions, affording a series of structurally stable spiropyrans and valuable arylquinones. The potential of this method is also demonstrated by scale-up synthesis and derivatization. Additionally, an unprecedented cycloruthenated complex has been identified as a key intermediate.
doi_str_mv 10.1039/D3CC03395C
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title Synthesis of spiropyrans and arylquinones via Ru( ii )-catalyzed condition-controlled coupling of 3-aryl-2 H -benzoxazinones with benzoquinones
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