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Performance analysis of three distinct Ni x V 2 O y single-phase nano self-assemblies for asymmetric supercapacitor fabrication and effective detection of low-concentration hazardous herbicide
Single-phase inorganic nanostructures with multiple applications are required for cost-effective, sustainable applications to save the environment from toxic activities. Nickel vanadate (Ni x V 2 O y ), possessing three phases, such as NiV 2 O 6 , Ni 2 V 2 O 7 , and Ni 3 V 2 O 8 , acts as an effecti...
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Published in: | Dalton transactions : an international journal of inorganic chemistry 2023-10, Vol.52 (40), p.14491-14509 |
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container_end_page | 14509 |
container_issue | 40 |
container_start_page | 14491 |
container_title | Dalton transactions : an international journal of inorganic chemistry |
container_volume | 52 |
creator | Seerangan Selvam, Govarthini Sthevan Kovil Pitchai, Jesman Ammasai, Kumaravel Dheivasigamani, Thangaraju |
description | Single-phase inorganic nanostructures with multiple applications are required for cost-effective, sustainable applications to save the environment from toxic activities. Nickel vanadate (Ni
x
V
2
O
y
), possessing three phases, such as NiV
2
O
6
, Ni
2
V
2
O
7
, and Ni
3
V
2
O
8
, acts as an effective electrode material and potential electrochemical sensors. Nickel vanadate phases (NiV
2
O
6
, Ni
2
V
2
O
7
, and Ni
3
V
2
O
8
) were synthesized through the gel-matrix technique, and their phase purity, crystallinity, morphology, optical properties,
etc
., were evaluated and studied. Electrochemical studies infer that NiV
2
O
6
exhibits the highest specific capacity of 251 C g
−1
(69.7 mA h g
−1
) at 1 A g
−1
compared to the other nickel vanadate phases and provides better cyclic stability of 80.19% for 5000 cycles. The asymmetric supercapacitor device fabricated from NiV
2
O
6
results in a specific capacity of 189 C g
−1
(52.5 mA h g
−1
), energy density of 59.06 W h kg
−1
, and a power density of 1125 W kg
−1
with a capacitive retention rate of 74.91% and coulombic efficiency of 99.61% for 10 000 cycles. The electrochemical detection potential of Ni
x
V
2
O
y
in bifenox herbicide has been studied with all the synthesized nanostructures. Among them, NiV
2
O
6
-based sensor probes demonstrated excellent characteristics, including high sensing current and low detection limits of 0.6 nM with a linear range of 1–57 nM. The real-time herbicide detection of NiV
2
O
6
in live samples was checked with freshly harvested potatoes. This advancement further enhances the utilization of Ni
x
V
2
O
y
materials for electrochemical applications. |
doi_str_mv | 10.1039/D3DT02384B |
format | article |
fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D3DT02384B</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1039_D3DT02384B</sourcerecordid><originalsourceid>FETCH-LOGICAL-c76B-241f1385a2b63fa371e5642eb12fc30f8b822f7bcc137516a06595e1ecfe8c5b3</originalsourceid><addsrcrecordid>eNpFUMtKA0EQXETBGL34BX0WVuexrxxN4gvEeAheQ-9sjzuyjzA9UePX-WluiOipi6qmqqgoOpfiUgo9uZrr-VIoXSTTg2gkkzyPJ0onh39YZcfRCfObEEqJVI2i72fytvctdoYAO2y27Bh6C6H2RFA5Dq4zAZ4cfMILKFjAFth1rw3F6xqZoMOuB6bGxshMbdk4YhgsAXnbthS8M8CbNXmDazQuDIrFcmAxuL4bMisga8kE9z7kUdihgR8qNP1HbPqhWBf8_rnGL_RVv2GoyZfOuIpOoyOLDdPZ7x1Hy9ub5ew-flzcPcyuH2OTZ9NYJdJKXaSoykxb1LmkNEsUlVJZo4UtykIpm5fGSJ2nMkORpZOUJBlLhUlLPY4u9rbG98ye7GrtXYt-u5JitZt-9T-9_gG4unuy</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Performance analysis of three distinct Ni x V 2 O y single-phase nano self-assemblies for asymmetric supercapacitor fabrication and effective detection of low-concentration hazardous herbicide</title><source>Royal Society of Chemistry</source><creator>Seerangan Selvam, Govarthini ; Sthevan Kovil Pitchai, Jesman ; Ammasai, Kumaravel ; Dheivasigamani, Thangaraju</creator><creatorcontrib>Seerangan Selvam, Govarthini ; Sthevan Kovil Pitchai, Jesman ; Ammasai, Kumaravel ; Dheivasigamani, Thangaraju</creatorcontrib><description>Single-phase inorganic nanostructures with multiple applications are required for cost-effective, sustainable applications to save the environment from toxic activities. Nickel vanadate (Ni
x
V
2
O
y
), possessing three phases, such as NiV
2
O
6
, Ni
2
V
2
O
7
, and Ni
3
V
2
O
8
, acts as an effective electrode material and potential electrochemical sensors. Nickel vanadate phases (NiV
2
O
6
, Ni
2
V
2
O
7
, and Ni
3
V
2
O
8
) were synthesized through the gel-matrix technique, and their phase purity, crystallinity, morphology, optical properties,
etc
., were evaluated and studied. Electrochemical studies infer that NiV
2
O
6
exhibits the highest specific capacity of 251 C g
−1
(69.7 mA h g
−1
) at 1 A g
−1
compared to the other nickel vanadate phases and provides better cyclic stability of 80.19% for 5000 cycles. The asymmetric supercapacitor device fabricated from NiV
2
O
6
results in a specific capacity of 189 C g
−1
(52.5 mA h g
−1
), energy density of 59.06 W h kg
−1
, and a power density of 1125 W kg
−1
with a capacitive retention rate of 74.91% and coulombic efficiency of 99.61% for 10 000 cycles. The electrochemical detection potential of Ni
x
V
2
O
y
in bifenox herbicide has been studied with all the synthesized nanostructures. Among them, NiV
2
O
6
-based sensor probes demonstrated excellent characteristics, including high sensing current and low detection limits of 0.6 nM with a linear range of 1–57 nM. The real-time herbicide detection of NiV
2
O
6
in live samples was checked with freshly harvested potatoes. This advancement further enhances the utilization of Ni
x
V
2
O
y
materials for electrochemical applications.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/D3DT02384B</identifier><language>eng</language><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-10, Vol.52 (40), p.14491-14509</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c76B-241f1385a2b63fa371e5642eb12fc30f8b822f7bcc137516a06595e1ecfe8c5b3</citedby><cites>FETCH-LOGICAL-c76B-241f1385a2b63fa371e5642eb12fc30f8b822f7bcc137516a06595e1ecfe8c5b3</cites><orcidid>0000-0003-1928-3779</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Seerangan Selvam, Govarthini</creatorcontrib><creatorcontrib>Sthevan Kovil Pitchai, Jesman</creatorcontrib><creatorcontrib>Ammasai, Kumaravel</creatorcontrib><creatorcontrib>Dheivasigamani, Thangaraju</creatorcontrib><title>Performance analysis of three distinct Ni x V 2 O y single-phase nano self-assemblies for asymmetric supercapacitor fabrication and effective detection of low-concentration hazardous herbicide</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Single-phase inorganic nanostructures with multiple applications are required for cost-effective, sustainable applications to save the environment from toxic activities. Nickel vanadate (Ni
x
V
2
O
y
), possessing three phases, such as NiV
2
O
6
, Ni
2
V
2
O
7
, and Ni
3
V
2
O
8
, acts as an effective electrode material and potential electrochemical sensors. Nickel vanadate phases (NiV
2
O
6
, Ni
2
V
2
O
7
, and Ni
3
V
2
O
8
) were synthesized through the gel-matrix technique, and their phase purity, crystallinity, morphology, optical properties,
etc
., were evaluated and studied. Electrochemical studies infer that NiV
2
O
6
exhibits the highest specific capacity of 251 C g
−1
(69.7 mA h g
−1
) at 1 A g
−1
compared to the other nickel vanadate phases and provides better cyclic stability of 80.19% for 5000 cycles. The asymmetric supercapacitor device fabricated from NiV
2
O
6
results in a specific capacity of 189 C g
−1
(52.5 mA h g
−1
), energy density of 59.06 W h kg
−1
, and a power density of 1125 W kg
−1
with a capacitive retention rate of 74.91% and coulombic efficiency of 99.61% for 10 000 cycles. The electrochemical detection potential of Ni
x
V
2
O
y
in bifenox herbicide has been studied with all the synthesized nanostructures. Among them, NiV
2
O
6
-based sensor probes demonstrated excellent characteristics, including high sensing current and low detection limits of 0.6 nM with a linear range of 1–57 nM. The real-time herbicide detection of NiV
2
O
6
in live samples was checked with freshly harvested potatoes. This advancement further enhances the utilization of Ni
x
V
2
O
y
materials for electrochemical applications.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpFUMtKA0EQXETBGL34BX0WVuexrxxN4gvEeAheQ-9sjzuyjzA9UePX-WluiOipi6qmqqgoOpfiUgo9uZrr-VIoXSTTg2gkkzyPJ0onh39YZcfRCfObEEqJVI2i72fytvctdoYAO2y27Bh6C6H2RFA5Dq4zAZ4cfMILKFjAFth1rw3F6xqZoMOuB6bGxshMbdk4YhgsAXnbthS8M8CbNXmDazQuDIrFcmAxuL4bMisga8kE9z7kUdihgR8qNP1HbPqhWBf8_rnGL_RVv2GoyZfOuIpOoyOLDdPZ7x1Hy9ub5ew-flzcPcyuH2OTZ9NYJdJKXaSoykxb1LmkNEsUlVJZo4UtykIpm5fGSJ2nMkORpZOUJBlLhUlLPY4u9rbG98ye7GrtXYt-u5JitZt-9T-9_gG4unuy</recordid><startdate>20231017</startdate><enddate>20231017</enddate><creator>Seerangan Selvam, Govarthini</creator><creator>Sthevan Kovil Pitchai, Jesman</creator><creator>Ammasai, Kumaravel</creator><creator>Dheivasigamani, Thangaraju</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1928-3779</orcidid></search><sort><creationdate>20231017</creationdate><title>Performance analysis of three distinct Ni x V 2 O y single-phase nano self-assemblies for asymmetric supercapacitor fabrication and effective detection of low-concentration hazardous herbicide</title><author>Seerangan Selvam, Govarthini ; Sthevan Kovil Pitchai, Jesman ; Ammasai, Kumaravel ; Dheivasigamani, Thangaraju</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c76B-241f1385a2b63fa371e5642eb12fc30f8b822f7bcc137516a06595e1ecfe8c5b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Seerangan Selvam, Govarthini</creatorcontrib><creatorcontrib>Sthevan Kovil Pitchai, Jesman</creatorcontrib><creatorcontrib>Ammasai, Kumaravel</creatorcontrib><creatorcontrib>Dheivasigamani, Thangaraju</creatorcontrib><collection>CrossRef</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Seerangan Selvam, Govarthini</au><au>Sthevan Kovil Pitchai, Jesman</au><au>Ammasai, Kumaravel</au><au>Dheivasigamani, Thangaraju</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Performance analysis of three distinct Ni x V 2 O y single-phase nano self-assemblies for asymmetric supercapacitor fabrication and effective detection of low-concentration hazardous herbicide</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2023-10-17</date><risdate>2023</risdate><volume>52</volume><issue>40</issue><spage>14491</spage><epage>14509</epage><pages>14491-14509</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Single-phase inorganic nanostructures with multiple applications are required for cost-effective, sustainable applications to save the environment from toxic activities. Nickel vanadate (Ni
x
V
2
O
y
), possessing three phases, such as NiV
2
O
6
, Ni
2
V
2
O
7
, and Ni
3
V
2
O
8
, acts as an effective electrode material and potential electrochemical sensors. Nickel vanadate phases (NiV
2
O
6
, Ni
2
V
2
O
7
, and Ni
3
V
2
O
8
) were synthesized through the gel-matrix technique, and their phase purity, crystallinity, morphology, optical properties,
etc
., were evaluated and studied. Electrochemical studies infer that NiV
2
O
6
exhibits the highest specific capacity of 251 C g
−1
(69.7 mA h g
−1
) at 1 A g
−1
compared to the other nickel vanadate phases and provides better cyclic stability of 80.19% for 5000 cycles. The asymmetric supercapacitor device fabricated from NiV
2
O
6
results in a specific capacity of 189 C g
−1
(52.5 mA h g
−1
), energy density of 59.06 W h kg
−1
, and a power density of 1125 W kg
−1
with a capacitive retention rate of 74.91% and coulombic efficiency of 99.61% for 10 000 cycles. The electrochemical detection potential of Ni
x
V
2
O
y
in bifenox herbicide has been studied with all the synthesized nanostructures. Among them, NiV
2
O
6
-based sensor probes demonstrated excellent characteristics, including high sensing current and low detection limits of 0.6 nM with a linear range of 1–57 nM. The real-time herbicide detection of NiV
2
O
6
in live samples was checked with freshly harvested potatoes. This advancement further enhances the utilization of Ni
x
V
2
O
y
materials for electrochemical applications.</abstract><doi>10.1039/D3DT02384B</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0003-1928-3779</orcidid></addata></record> |
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language | eng |
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source | Royal Society of Chemistry |
title | Performance analysis of three distinct Ni x V 2 O y single-phase nano self-assemblies for asymmetric supercapacitor fabrication and effective detection of low-concentration hazardous herbicide |
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