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Co-Mo alloy oxide decorated carbon cloth as lithium host for dendrite-free lithium metal anode
Lithium metal batteries are a promising energy storage solution for next-generation high-efficiency and high-energy-density batteries due to their ultrahigh theoretical capacity (3860 mA h g −1 ) and low anode potential (−3.04 V vs. the standard hydrogen electrode). Unfortunately, severe safety haza...
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| Published in: | Sustainable energy & fuels 2023-05, Vol.7 (1), p.2357-2367 |
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| Main Authors: | , , , , , , |
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| cited_by | cdi_FETCH-LOGICAL-c281t-8dd860f6799e35d18ca2c1f150a572ef69ef92665d4598feba30430c382a584a3 |
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| cites | cdi_FETCH-LOGICAL-c281t-8dd860f6799e35d18ca2c1f150a572ef69ef92665d4598feba30430c382a584a3 |
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| container_title | Sustainable energy & fuels |
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| creator | Wang, Xingjie Liu, Shuai Shi, Jing Huang, Minghua Shi, Zhicheng Wang, Huanlei Yan, Zhenhua |
| description | Lithium metal batteries are a promising energy storage solution for next-generation high-efficiency and high-energy-density batteries due to their ultrahigh theoretical capacity (3860 mA h g
−1
) and low anode potential (−3.04 V
vs.
the standard hydrogen electrode). Unfortunately, severe safety hazards have been caused by Li dendrite growth during long-term cycling. Here, we have designed a controllable and electrolyte-wetted composite anode
via
molten Li infusion into Co-Mo alloy oxide layer (CMO)-coated commercial carbon cloth (CC). Benefiting from the superior lithiophilicity of Co-Mo alloy oxides, the composite anode allows the fast infusion of molten Li at a low temperature of 250 °C. Symmetrical cells assembled with composite anodes afford stable cycling for 2500 h at 1 mA cm
−2
with 1 mA h cm
−2
. Full cells coupled with an LiFePO
4
(LFP) cathode delivered a reversible capacity of 139.36 mA h g
−1
after 500 cycles. In this work, we present a systematic study of the effect of the Co-Mo alloy oxide layer on carbon cloth on battery performance. Moreover, we not only prepared a dendrite-free lithium metal composite anode, but also provided a new strategy for the controllable modification of an alloy oxide layer on a current collector.
The carbon cloth modified with Co-Mo alloy oxide could enhance the performance of Li-metal battery anode. The Full cell coupled with LiFePO
4
cathode could deliver a reversible capacity of 139.36 mA h g
−1
after 500 cycles. |
| doi_str_mv | 10.1039/d3se00254c |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D3SE00254C</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2813870178</sourcerecordid><originalsourceid>FETCH-LOGICAL-c281t-8dd860f6799e35d18ca2c1f150a572ef69ef92665d4598feba30430c382a584a3</originalsourceid><addsrcrecordid>eNpN0M9LwzAUB_AgCo65i3ch4E2o5kfTJkepmwoTD-rVkiUvtKNrZpKB---tVqan9-B9eF_4InROyTUlXN1YHoEQJnJzhCaMK5nlirDjf_spmsW4JgOiLGeinKD3ymdPHuuu83vsP1sL2ILxQSew2Oiw8j02nU8N1hF3bWra3QY3PibsfBhob0ObIHMB4HDeQNId1r23cIZOnO4izH7nFL0t5q_VQ7Z8vn-sbpeZYZKmTForC-KKUingwlJpNDPUUUG0KBm4QoFTrCiEzYWSDlaak5wTwyXTQuaaT9Hl-Hcb_McOYqrXfhf6IbIeArgsCS3loK5GZYKPMYCrt6Hd6LCvKam_K6zv-Mv8p8JqwBcjDtEc3F_F_Avv5mzm</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2813870178</pqid></control><display><type>article</type><title>Co-Mo alloy oxide decorated carbon cloth as lithium host for dendrite-free lithium metal anode</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Wang, Xingjie ; Liu, Shuai ; Shi, Jing ; Huang, Minghua ; Shi, Zhicheng ; Wang, Huanlei ; Yan, Zhenhua</creator><creatorcontrib>Wang, Xingjie ; Liu, Shuai ; Shi, Jing ; Huang, Minghua ; Shi, Zhicheng ; Wang, Huanlei ; Yan, Zhenhua</creatorcontrib><description>Lithium metal batteries are a promising energy storage solution for next-generation high-efficiency and high-energy-density batteries due to their ultrahigh theoretical capacity (3860 mA h g
−1
) and low anode potential (−3.04 V
vs.
the standard hydrogen electrode). Unfortunately, severe safety hazards have been caused by Li dendrite growth during long-term cycling. Here, we have designed a controllable and electrolyte-wetted composite anode
via
molten Li infusion into Co-Mo alloy oxide layer (CMO)-coated commercial carbon cloth (CC). Benefiting from the superior lithiophilicity of Co-Mo alloy oxides, the composite anode allows the fast infusion of molten Li at a low temperature of 250 °C. Symmetrical cells assembled with composite anodes afford stable cycling for 2500 h at 1 mA cm
−2
with 1 mA h cm
−2
. Full cells coupled with an LiFePO
4
(LFP) cathode delivered a reversible capacity of 139.36 mA h g
−1
after 500 cycles. In this work, we present a systematic study of the effect of the Co-Mo alloy oxide layer on carbon cloth on battery performance. Moreover, we not only prepared a dendrite-free lithium metal composite anode, but also provided a new strategy for the controllable modification of an alloy oxide layer on a current collector.
The carbon cloth modified with Co-Mo alloy oxide could enhance the performance of Li-metal battery anode. The Full cell coupled with LiFePO
4
cathode could deliver a reversible capacity of 139.36 mA h g
−1
after 500 cycles.</description><identifier>ISSN: 2398-4902</identifier><identifier>EISSN: 2398-4902</identifier><identifier>DOI: 10.1039/d3se00254c</identifier><language>eng</language><publisher>London: Royal Society of Chemistry</publisher><subject>Anodes ; Batteries ; Carbon ; Cloth ; Composite materials ; Controllability ; Cycles ; Dendrites ; Electrolytic cells ; Energy storage ; Lithium ; Lithium batteries ; Low temperature ; Metal oxides</subject><ispartof>Sustainable energy & fuels, 2023-05, Vol.7 (1), p.2357-2367</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-8dd860f6799e35d18ca2c1f150a572ef69ef92665d4598feba30430c382a584a3</citedby><cites>FETCH-LOGICAL-c281t-8dd860f6799e35d18ca2c1f150a572ef69ef92665d4598feba30430c382a584a3</cites><orcidid>0000-0002-8862-2116 ; 0000-0002-9622-3131 ; 0000-0002-5001-1862 ; 0000-0002-8420-0100 ; 0000-0001-8218-1762 ; 0000-0002-1309-5606</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wang, Xingjie</creatorcontrib><creatorcontrib>Liu, Shuai</creatorcontrib><creatorcontrib>Shi, Jing</creatorcontrib><creatorcontrib>Huang, Minghua</creatorcontrib><creatorcontrib>Shi, Zhicheng</creatorcontrib><creatorcontrib>Wang, Huanlei</creatorcontrib><creatorcontrib>Yan, Zhenhua</creatorcontrib><title>Co-Mo alloy oxide decorated carbon cloth as lithium host for dendrite-free lithium metal anode</title><title>Sustainable energy & fuels</title><description>Lithium metal batteries are a promising energy storage solution for next-generation high-efficiency and high-energy-density batteries due to their ultrahigh theoretical capacity (3860 mA h g
−1
) and low anode potential (−3.04 V
vs.
the standard hydrogen electrode). Unfortunately, severe safety hazards have been caused by Li dendrite growth during long-term cycling. Here, we have designed a controllable and electrolyte-wetted composite anode
via
molten Li infusion into Co-Mo alloy oxide layer (CMO)-coated commercial carbon cloth (CC). Benefiting from the superior lithiophilicity of Co-Mo alloy oxides, the composite anode allows the fast infusion of molten Li at a low temperature of 250 °C. Symmetrical cells assembled with composite anodes afford stable cycling for 2500 h at 1 mA cm
−2
with 1 mA h cm
−2
. Full cells coupled with an LiFePO
4
(LFP) cathode delivered a reversible capacity of 139.36 mA h g
−1
after 500 cycles. In this work, we present a systematic study of the effect of the Co-Mo alloy oxide layer on carbon cloth on battery performance. Moreover, we not only prepared a dendrite-free lithium metal composite anode, but also provided a new strategy for the controllable modification of an alloy oxide layer on a current collector.
The carbon cloth modified with Co-Mo alloy oxide could enhance the performance of Li-metal battery anode. The Full cell coupled with LiFePO
4
cathode could deliver a reversible capacity of 139.36 mA h g
−1
after 500 cycles.</description><subject>Anodes</subject><subject>Batteries</subject><subject>Carbon</subject><subject>Cloth</subject><subject>Composite materials</subject><subject>Controllability</subject><subject>Cycles</subject><subject>Dendrites</subject><subject>Electrolytic cells</subject><subject>Energy storage</subject><subject>Lithium</subject><subject>Lithium batteries</subject><subject>Low temperature</subject><subject>Metal oxides</subject><issn>2398-4902</issn><issn>2398-4902</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpN0M9LwzAUB_AgCo65i3ch4E2o5kfTJkepmwoTD-rVkiUvtKNrZpKB---tVqan9-B9eF_4InROyTUlXN1YHoEQJnJzhCaMK5nlirDjf_spmsW4JgOiLGeinKD3ymdPHuuu83vsP1sL2ILxQSew2Oiw8j02nU8N1hF3bWra3QY3PibsfBhob0ObIHMB4HDeQNId1r23cIZOnO4izH7nFL0t5q_VQ7Z8vn-sbpeZYZKmTForC-KKUingwlJpNDPUUUG0KBm4QoFTrCiEzYWSDlaak5wTwyXTQuaaT9Hl-Hcb_McOYqrXfhf6IbIeArgsCS3loK5GZYKPMYCrt6Hd6LCvKam_K6zv-Mv8p8JqwBcjDtEc3F_F_Avv5mzm</recordid><startdate>20230516</startdate><enddate>20230516</enddate><creator>Wang, Xingjie</creator><creator>Liu, Shuai</creator><creator>Shi, Jing</creator><creator>Huang, Minghua</creator><creator>Shi, Zhicheng</creator><creator>Wang, Huanlei</creator><creator>Yan, Zhenhua</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7SP</scope><scope>7ST</scope><scope>7U6</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>L7M</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0002-8862-2116</orcidid><orcidid>https://orcid.org/0000-0002-9622-3131</orcidid><orcidid>https://orcid.org/0000-0002-5001-1862</orcidid><orcidid>https://orcid.org/0000-0002-8420-0100</orcidid><orcidid>https://orcid.org/0000-0001-8218-1762</orcidid><orcidid>https://orcid.org/0000-0002-1309-5606</orcidid></search><sort><creationdate>20230516</creationdate><title>Co-Mo alloy oxide decorated carbon cloth as lithium host for dendrite-free lithium metal anode</title><author>Wang, Xingjie ; Liu, Shuai ; Shi, Jing ; Huang, Minghua ; Shi, Zhicheng ; Wang, Huanlei ; Yan, Zhenhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-8dd860f6799e35d18ca2c1f150a572ef69ef92665d4598feba30430c382a584a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Anodes</topic><topic>Batteries</topic><topic>Carbon</topic><topic>Cloth</topic><topic>Composite materials</topic><topic>Controllability</topic><topic>Cycles</topic><topic>Dendrites</topic><topic>Electrolytic cells</topic><topic>Energy storage</topic><topic>Lithium</topic><topic>Lithium batteries</topic><topic>Low temperature</topic><topic>Metal oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xingjie</creatorcontrib><creatorcontrib>Liu, Shuai</creatorcontrib><creatorcontrib>Shi, Jing</creatorcontrib><creatorcontrib>Huang, Minghua</creatorcontrib><creatorcontrib>Shi, Zhicheng</creatorcontrib><creatorcontrib>Wang, Huanlei</creatorcontrib><creatorcontrib>Yan, Zhenhua</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Sustainable energy & fuels</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xingjie</au><au>Liu, Shuai</au><au>Shi, Jing</au><au>Huang, Minghua</au><au>Shi, Zhicheng</au><au>Wang, Huanlei</au><au>Yan, Zhenhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Co-Mo alloy oxide decorated carbon cloth as lithium host for dendrite-free lithium metal anode</atitle><jtitle>Sustainable energy & fuels</jtitle><date>2023-05-16</date><risdate>2023</risdate><volume>7</volume><issue>1</issue><spage>2357</spage><epage>2367</epage><pages>2357-2367</pages><issn>2398-4902</issn><eissn>2398-4902</eissn><abstract>Lithium metal batteries are a promising energy storage solution for next-generation high-efficiency and high-energy-density batteries due to their ultrahigh theoretical capacity (3860 mA h g
−1
) and low anode potential (−3.04 V
vs.
the standard hydrogen electrode). Unfortunately, severe safety hazards have been caused by Li dendrite growth during long-term cycling. Here, we have designed a controllable and electrolyte-wetted composite anode
via
molten Li infusion into Co-Mo alloy oxide layer (CMO)-coated commercial carbon cloth (CC). Benefiting from the superior lithiophilicity of Co-Mo alloy oxides, the composite anode allows the fast infusion of molten Li at a low temperature of 250 °C. Symmetrical cells assembled with composite anodes afford stable cycling for 2500 h at 1 mA cm
−2
with 1 mA h cm
−2
. Full cells coupled with an LiFePO
4
(LFP) cathode delivered a reversible capacity of 139.36 mA h g
−1
after 500 cycles. In this work, we present a systematic study of the effect of the Co-Mo alloy oxide layer on carbon cloth on battery performance. Moreover, we not only prepared a dendrite-free lithium metal composite anode, but also provided a new strategy for the controllable modification of an alloy oxide layer on a current collector.
The carbon cloth modified with Co-Mo alloy oxide could enhance the performance of Li-metal battery anode. The Full cell coupled with LiFePO
4
cathode could deliver a reversible capacity of 139.36 mA h g
−1
after 500 cycles.</abstract><cop>London</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3se00254c</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-8862-2116</orcidid><orcidid>https://orcid.org/0000-0002-9622-3131</orcidid><orcidid>https://orcid.org/0000-0002-5001-1862</orcidid><orcidid>https://orcid.org/0000-0002-8420-0100</orcidid><orcidid>https://orcid.org/0000-0001-8218-1762</orcidid><orcidid>https://orcid.org/0000-0002-1309-5606</orcidid></addata></record> |
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| identifier | ISSN: 2398-4902 |
| ispartof | Sustainable energy & fuels, 2023-05, Vol.7 (1), p.2357-2367 |
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| recordid | cdi_crossref_primary_10_1039_D3SE00254C |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Anodes Batteries Carbon Cloth Composite materials Controllability Cycles Dendrites Electrolytic cells Energy storage Lithium Lithium batteries Low temperature Metal oxides |
| title | Co-Mo alloy oxide decorated carbon cloth as lithium host for dendrite-free lithium metal anode |
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