Gold carbonyl cations and beyond: homoleptic gold(I) complexes with P 4 and P 4 S 3 and the half-sandwich cation [Au(C 6 H 6 )(CO)]

Oxidation of Au with the synergistic Ag /0.5 I system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the perfluoroalkoxyaluminate salt of the [Au(CO) ] cation known from superacid chemistry. This [Au(CO) ] salt proved to be an excellent 'naked' Au -synthon yielding com...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-05, Vol.60 (41), p.5403-5406
Main Authors: Schmitt, Manuel, Nestle, Sarah, Radtke, Valentin, Krossing, Ingo
Format: Article
Language:English
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Summary:Oxidation of Au with the synergistic Ag /0.5 I system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the perfluoroalkoxyaluminate salt of the [Au(CO) ] cation known from superacid chemistry. This [Au(CO) ] salt proved to be an excellent 'naked' Au -synthon yielding complex salts with [Au(η -P ) ] , [Au(η -P S ) ] and half-sandwich [Au(η -C H )(CO)] cation.
ISSN:1359-7345
1364-548X
DOI:10.1039/D4CC01374C