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Modulated synthesis of hcp MOFs for preferential CO 2 capture

We herein show that the μ -OH bridging groups in the double M O (OH) clusters of hcp UiO-66 could act as a preferential CO sorption site, compared to fcu UiO-66. As such, hcp-UiO-66-0.015 shows a high binary CO sorption capacity of 0.31 mmol g and CO /N (15/85) mixture selectivity of 87 at 298 K and...

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Published in:Chemical communications (Cambridge, England) England), 2024-08, Vol.60 (64), p.8395-8398
Main Authors: Zhang, Jiaxi, Khan, Mehak Nawaz, Hu, Zhigang, Zou, Jianxin
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creator Zhang, Jiaxi
Khan, Mehak Nawaz
Hu, Zhigang
Zou, Jianxin
description We herein show that the μ -OH bridging groups in the double M O (OH) clusters of hcp UiO-66 could act as a preferential CO sorption site, compared to fcu UiO-66. As such, hcp-UiO-66-0.015 shows a high binary CO sorption capacity of 0.31 mmol g and CO /N (15/85) mixture selectivity of 87 at 298 K and 1 bar, which holds great potential for post-combustion CO capture.
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