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Exploring porosity in a flexible 3D organic-inorganic {Zn(4DPNDI)[W(CN)]} coordination network
A 2D cyanido-bridged architecture Zn II -[W V (CN) 8 ] 3− is smoothly pillared by N , N ′-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (4DPNDI) into 3D hybrid porous coordination polymer (PCP) {Zn II 3 (DMA) 6 [W V (CN) 8 ] 2 (4DPNDI)·8DMA}. It shows significant uptake of H 2 O, MeOH or CHC...
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| Published in: | Chemical communications (Cambridge, England) England), 2024-09, Vol.6 (77), p.174-177 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 177 |
| container_issue | 77 |
| container_start_page | 174 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 6 |
| creator | J drzejowska, Katarzyna Kobylarczyk, Jedrzej Muzio, Tadeusz M Nowicka, Beata J drzejowski, Damian Matoga, Dariusz Gawe, Bart omiej Podgajny, Robert |
| description | A 2D cyanido-bridged architecture Zn
II
-[W
V
(CN)
8
]
3−
is smoothly pillared by
N
,
N
′-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (4DPNDI) into 3D hybrid porous coordination polymer (PCP) {Zn
II
3
(DMA)
6
[W
V
(CN)
8
]
2
(4DPNDI)·8DMA}. It shows significant uptake of H
2
O, MeOH or CHCl
3
vapours with easy regeneration to the native form, and breathing-type CO
2
adsorption contrasting non-porosity towards N
2
, providing a new example of a highly flexible porous material.
2D Zn
II
3
[W
V
(CN)
8
]
2
·DMA CP was converted into flexible regenerable 3D 3rd-generation PCP Zn
II
3
(4DPNDI)[W
V
(CN)
8
]
2
·DMA disclosing water, methanol, chloroform, and CO
2
sorption ability. |
| doi_str_mv | 10.1039/d4cc03141e |
| format | article |
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II
-[W
V
(CN)
8
]
3−
is smoothly pillared by
N
,
N
′-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (4DPNDI) into 3D hybrid porous coordination polymer (PCP) {Zn
II
3
(DMA)
6
[W
V
(CN)
8
]
2
(4DPNDI)·8DMA}. It shows significant uptake of H
2
O, MeOH or CHCl
3
vapours with easy regeneration to the native form, and breathing-type CO
2
adsorption contrasting non-porosity towards N
2
, providing a new example of a highly flexible porous material.
2D Zn
II
3
[W
V
(CN)
8
]
2
·DMA CP was converted into flexible regenerable 3D 3rd-generation PCP Zn
II
3
(4DPNDI)[W
V
(CN)
8
]
2
·DMA disclosing water, methanol, chloroform, and CO
2
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II
-[W
V
(CN)
8
]
3−
is smoothly pillared by
N
,
N
′-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (4DPNDI) into 3D hybrid porous coordination polymer (PCP) {Zn
II
3
(DMA)
6
[W
V
(CN)
8
]
2
(4DPNDI)·8DMA}. It shows significant uptake of H
2
O, MeOH or CHCl
3
vapours with easy regeneration to the native form, and breathing-type CO
2
adsorption contrasting non-porosity towards N
2
, providing a new example of a highly flexible porous material.
2D Zn
II
3
[W
V
(CN)
8
]
2
·DMA CP was converted into flexible regenerable 3D 3rd-generation PCP Zn
II
3
(4DPNDI)[W
V
(CN)
8
]
2
·DMA disclosing water, methanol, chloroform, and CO
2
sorption ability.</description><subject>Chloroform</subject><subject>Coordination polymers</subject><subject>Porosity</subject><subject>Porous materials</subject><issn>1359-7345</issn><issn>1364-548X</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0VGLEzEQB_Agiq2nL74rAV96wmqSSbLJo2x7WiinD4ricS7ZbFrS2yY12XJ3iN_dra13YF5mYH4Mwz8IPafkDSWg37bcWgKUU_cAjSlIXgiuvj3c90IXJXAxQk9yXpPhUaEeoxFoBlpqOUY_ZjfbLiYfVngbU8y-v8U-YIOXnbvxTecwTHFMKxO8LXw4dvjX9zDh00_n0_npxddJdX56-RvbGFPrg-l9DDi4_jqmq6fo0dJ02T071hP05Wz2ufpQLD6-n1fvFoVlTPZF61pDtBKNYFKWQrKysYoDcCJANmVTLoERZlTZNqJRxIAzsjTKat1qIIzBCZoc9m5T_Llzua83PlvXdSa4uMs1UEIZUFbCQF_9R9dxl8Jw3V4pIRQXdFCvD8oOoeTklvU2-Y1JtzUl9T71esqr6m_qswG_PK7cNRvX3tF_MQ_gxQGkbO-m998GfwDeaYQu</recordid><startdate>20240924</startdate><enddate>20240924</enddate><creator>J drzejowska, Katarzyna</creator><creator>Kobylarczyk, Jedrzej</creator><creator>Muzio, Tadeusz M</creator><creator>Nowicka, Beata</creator><creator>J drzejowski, Damian</creator><creator>Matoga, Dariusz</creator><creator>Gawe, Bart omiej</creator><creator>Podgajny, Robert</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1426-2477</orcidid><orcidid>https://orcid.org/0000-0002-0064-5541</orcidid><orcidid>https://orcid.org/0000-0003-1611-0119</orcidid><orcidid>https://orcid.org/0000-0002-1745-3562</orcidid><orcidid>https://orcid.org/0000-0002-0607-8779</orcidid><orcidid>https://orcid.org/0000-0001-7457-6799</orcidid><orcidid>https://orcid.org/0000-0002-5378-9215</orcidid></search><sort><creationdate>20240924</creationdate><title>Exploring porosity in a flexible 3D organic-inorganic {Zn(4DPNDI)[W(CN)]} coordination network</title><author>J drzejowska, Katarzyna ; Kobylarczyk, Jedrzej ; Muzio, Tadeusz M ; Nowicka, Beata ; J drzejowski, Damian ; Matoga, Dariusz ; Gawe, Bart omiej ; Podgajny, Robert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c226t-deda0985b526675627bc843340536b7b7f3202a87db5b80a3ea67a8c99d930223</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Chloroform</topic><topic>Coordination polymers</topic><topic>Porosity</topic><topic>Porous materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>J drzejowska, Katarzyna</creatorcontrib><creatorcontrib>Kobylarczyk, Jedrzej</creatorcontrib><creatorcontrib>Muzio, Tadeusz M</creatorcontrib><creatorcontrib>Nowicka, Beata</creatorcontrib><creatorcontrib>J drzejowski, Damian</creatorcontrib><creatorcontrib>Matoga, Dariusz</creatorcontrib><creatorcontrib>Gawe, Bart omiej</creatorcontrib><creatorcontrib>Podgajny, Robert</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>J drzejowska, Katarzyna</au><au>Kobylarczyk, Jedrzej</au><au>Muzio, Tadeusz M</au><au>Nowicka, Beata</au><au>J drzejowski, Damian</au><au>Matoga, Dariusz</au><au>Gawe, Bart omiej</au><au>Podgajny, Robert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Exploring porosity in a flexible 3D organic-inorganic {Zn(4DPNDI)[W(CN)]} coordination network</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2024-09-24</date><risdate>2024</risdate><volume>6</volume><issue>77</issue><spage>174</spage><epage>177</epage><pages>174-177</pages><issn>1359-7345</issn><issn>1364-548X</issn><eissn>1364-548X</eissn><abstract>A 2D cyanido-bridged architecture Zn
II
-[W
V
(CN)
8
]
3−
is smoothly pillared by
N
,
N
′-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (4DPNDI) into 3D hybrid porous coordination polymer (PCP) {Zn
II
3
(DMA)
6
[W
V
(CN)
8
]
2
(4DPNDI)·8DMA}. It shows significant uptake of H
2
O, MeOH or CHCl
3
vapours with easy regeneration to the native form, and breathing-type CO
2
adsorption contrasting non-porosity towards N
2
, providing a new example of a highly flexible porous material.
2D Zn
II
3
[W
V
(CN)
8
]
2
·DMA CP was converted into flexible regenerable 3D 3rd-generation PCP Zn
II
3
(4DPNDI)[W
V
(CN)
8
]
2
·DMA disclosing water, methanol, chloroform, and CO
2
sorption ability.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39239696</pmid><doi>10.1039/d4cc03141e</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-1426-2477</orcidid><orcidid>https://orcid.org/0000-0002-0064-5541</orcidid><orcidid>https://orcid.org/0000-0003-1611-0119</orcidid><orcidid>https://orcid.org/0000-0002-1745-3562</orcidid><orcidid>https://orcid.org/0000-0002-0607-8779</orcidid><orcidid>https://orcid.org/0000-0001-7457-6799</orcidid><orcidid>https://orcid.org/0000-0002-5378-9215</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-09, Vol.6 (77), p.174-177 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D4CC03141E |
| source | Royal Society of Chemistry |
| subjects | Chloroform Coordination polymers Porosity Porous materials |
| title | Exploring porosity in a flexible 3D organic-inorganic {Zn(4DPNDI)[W(CN)]} coordination network |
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