The cubic structure of Li 3 As stabilized by substitution - Li 8 TtAs 4 (Tt = Si, Ge) and Li 14 TtAs 6 (Tt = Si, Ge, Sn) and their lithium ion conductivity

The new lithium arsenidotetrelates Li SiAs , Li GeAs , Li SiAs , Li GeAs and Li SnAs were synthesized ball milling and structurally characterized by Rietveld analysis of X-ray powder diffraction data. The aliovalent substitution of lithium in hexagonal Li As by introducing a tetravalent tetrel catio...

Full description

Saved in:
Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2024-07, Vol.53 (27), p.11257-11263
Main Authors: Schmid, Martin, Wegner, Florian, De Giorgi, Claudia, Pielnhofer, Florian, Pfitzner, Arno
Format: Article
Language:English
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c581-77349e103b5113a921af537100f7187476c39d6aade0d6211706e3d2082539913
container_end_page 11263
container_issue 27
container_start_page 11257
container_title Dalton transactions : an international journal of inorganic chemistry
container_volume 53
creator Schmid, Martin
Wegner, Florian
De Giorgi, Claudia
Pielnhofer, Florian
Pfitzner, Arno
description The new lithium arsenidotetrelates Li SiAs , Li GeAs , Li SiAs , Li GeAs and Li SnAs were synthesized ball milling and structurally characterized by Rietveld analysis of X-ray powder diffraction data. The aliovalent substitution of lithium in hexagonal Li As by introducing a tetravalent tetrel cation stabilizes cubic structures for Li TtAs (Tt = Si, Ge) in the space group 3̄ and for the lithium richer compound Li TtAs (Tt = Si, Ge, Sn) in the higher symmetrical space group 3̄ (no. 225). Thermal properties of the arsenidotetrelates were investigated high temperature powder diffraction and differential thermal analysis revealing a decomposition process of the lithium richer arsenidotetrelate (Li TtAs → Li TtAs + 2Li As) into the lithium poorer arsenidotetrelates and lithium arsenide at moderate temperatures. Impedance spectroscopy shows moderate to good lithium ion conductivity for the lithium arsenidotetrelates.
doi_str_mv 10.1039/d4dt00664j
format article
fullrecord <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D4DT00664J</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>38687121</sourcerecordid><originalsourceid>FETCH-LOGICAL-c581-77349e103b5113a921af537100f7187476c39d6aade0d6211706e3d2082539913</originalsourceid><addsrcrecordid>eNpVkMFKw0AQhhdRbK1efACZo0qjO7ub3eTgobRalYKH5h6S7IZuadOS3Qj1VXxZE6OCpxnm__gZPkIukd4h5fG9FtpTKqVYH5EhCqWCmHFx_LczOSBnzq0pZYyG7JQMeCQjhQyH5DNZGSia3BbgfN0UvqkN7EpYWOAwce0xy-3GfhgN-QFckztvfePtroKggyJIfIsJuE48PMDSjmFubiCrdJei6GP5Lx7DsuoRvzK2ho31K9tsoSstdpVuv7Dv1h_OyUmZbZy5-Jkjkjw9JtPnYPE2f5lOFkERRhgoxUVsWhF5iMizmGFWhlwhpaXCSAklCx5rmWXaUC0ZoqLScM1oxEIex8hH5LavLeqdc7Up031tt1l9SJGmneB0JmbJt-DXFr7q4X2Tb43-Q3-N8i-4mXA4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>The cubic structure of Li 3 As stabilized by substitution - Li 8 TtAs 4 (Tt = Si, Ge) and Li 14 TtAs 6 (Tt = Si, Ge, Sn) and their lithium ion conductivity</title><source>Royal Society of Chemistry</source><creator>Schmid, Martin ; Wegner, Florian ; De Giorgi, Claudia ; Pielnhofer, Florian ; Pfitzner, Arno</creator><creatorcontrib>Schmid, Martin ; Wegner, Florian ; De Giorgi, Claudia ; Pielnhofer, Florian ; Pfitzner, Arno</creatorcontrib><description>The new lithium arsenidotetrelates Li SiAs , Li GeAs , Li SiAs , Li GeAs and Li SnAs were synthesized ball milling and structurally characterized by Rietveld analysis of X-ray powder diffraction data. The aliovalent substitution of lithium in hexagonal Li As by introducing a tetravalent tetrel cation stabilizes cubic structures for Li TtAs (Tt = Si, Ge) in the space group 3̄ and for the lithium richer compound Li TtAs (Tt = Si, Ge, Sn) in the higher symmetrical space group 3̄ (no. 225). Thermal properties of the arsenidotetrelates were investigated high temperature powder diffraction and differential thermal analysis revealing a decomposition process of the lithium richer arsenidotetrelate (Li TtAs → Li TtAs + 2Li As) into the lithium poorer arsenidotetrelates and lithium arsenide at moderate temperatures. Impedance spectroscopy shows moderate to good lithium ion conductivity for the lithium arsenidotetrelates.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d4dt00664j</identifier><identifier>PMID: 38687121</identifier><language>eng</language><publisher>England</publisher><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-07, Vol.53 (27), p.11257-11263</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c581-77349e103b5113a921af537100f7187476c39d6aade0d6211706e3d2082539913</cites><orcidid>0000-0001-5309-4301 ; 0000-0001-8653-7439</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38687121$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schmid, Martin</creatorcontrib><creatorcontrib>Wegner, Florian</creatorcontrib><creatorcontrib>De Giorgi, Claudia</creatorcontrib><creatorcontrib>Pielnhofer, Florian</creatorcontrib><creatorcontrib>Pfitzner, Arno</creatorcontrib><title>The cubic structure of Li 3 As stabilized by substitution - Li 8 TtAs 4 (Tt = Si, Ge) and Li 14 TtAs 6 (Tt = Si, Ge, Sn) and their lithium ion conductivity</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>The new lithium arsenidotetrelates Li SiAs , Li GeAs , Li SiAs , Li GeAs and Li SnAs were synthesized ball milling and structurally characterized by Rietveld analysis of X-ray powder diffraction data. The aliovalent substitution of lithium in hexagonal Li As by introducing a tetravalent tetrel cation stabilizes cubic structures for Li TtAs (Tt = Si, Ge) in the space group 3̄ and for the lithium richer compound Li TtAs (Tt = Si, Ge, Sn) in the higher symmetrical space group 3̄ (no. 225). Thermal properties of the arsenidotetrelates were investigated high temperature powder diffraction and differential thermal analysis revealing a decomposition process of the lithium richer arsenidotetrelate (Li TtAs → Li TtAs + 2Li As) into the lithium poorer arsenidotetrelates and lithium arsenide at moderate temperatures. Impedance spectroscopy shows moderate to good lithium ion conductivity for the lithium arsenidotetrelates.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpVkMFKw0AQhhdRbK1efACZo0qjO7ub3eTgobRalYKH5h6S7IZuadOS3Qj1VXxZE6OCpxnm__gZPkIukd4h5fG9FtpTKqVYH5EhCqWCmHFx_LczOSBnzq0pZYyG7JQMeCQjhQyH5DNZGSia3BbgfN0UvqkN7EpYWOAwce0xy-3GfhgN-QFckztvfePtroKggyJIfIsJuE48PMDSjmFubiCrdJei6GP5Lx7DsuoRvzK2ho31K9tsoSstdpVuv7Dv1h_OyUmZbZy5-Jkjkjw9JtPnYPE2f5lOFkERRhgoxUVsWhF5iMizmGFWhlwhpaXCSAklCx5rmWXaUC0ZoqLScM1oxEIex8hH5LavLeqdc7Up031tt1l9SJGmneB0JmbJt-DXFr7q4X2Tb43-Q3-N8i-4mXA4</recordid><startdate>20240709</startdate><enddate>20240709</enddate><creator>Schmid, Martin</creator><creator>Wegner, Florian</creator><creator>De Giorgi, Claudia</creator><creator>Pielnhofer, Florian</creator><creator>Pfitzner, Arno</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5309-4301</orcidid><orcidid>https://orcid.org/0000-0001-8653-7439</orcidid></search><sort><creationdate>20240709</creationdate><title>The cubic structure of Li 3 As stabilized by substitution - Li 8 TtAs 4 (Tt = Si, Ge) and Li 14 TtAs 6 (Tt = Si, Ge, Sn) and their lithium ion conductivity</title><author>Schmid, Martin ; Wegner, Florian ; De Giorgi, Claudia ; Pielnhofer, Florian ; Pfitzner, Arno</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c581-77349e103b5113a921af537100f7187476c39d6aade0d6211706e3d2082539913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schmid, Martin</creatorcontrib><creatorcontrib>Wegner, Florian</creatorcontrib><creatorcontrib>De Giorgi, Claudia</creatorcontrib><creatorcontrib>Pielnhofer, Florian</creatorcontrib><creatorcontrib>Pfitzner, Arno</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schmid, Martin</au><au>Wegner, Florian</au><au>De Giorgi, Claudia</au><au>Pielnhofer, Florian</au><au>Pfitzner, Arno</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The cubic structure of Li 3 As stabilized by substitution - Li 8 TtAs 4 (Tt = Si, Ge) and Li 14 TtAs 6 (Tt = Si, Ge, Sn) and their lithium ion conductivity</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2024-07-09</date><risdate>2024</risdate><volume>53</volume><issue>27</issue><spage>11257</spage><epage>11263</epage><pages>11257-11263</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The new lithium arsenidotetrelates Li SiAs , Li GeAs , Li SiAs , Li GeAs and Li SnAs were synthesized ball milling and structurally characterized by Rietveld analysis of X-ray powder diffraction data. The aliovalent substitution of lithium in hexagonal Li As by introducing a tetravalent tetrel cation stabilizes cubic structures for Li TtAs (Tt = Si, Ge) in the space group 3̄ and for the lithium richer compound Li TtAs (Tt = Si, Ge, Sn) in the higher symmetrical space group 3̄ (no. 225). Thermal properties of the arsenidotetrelates were investigated high temperature powder diffraction and differential thermal analysis revealing a decomposition process of the lithium richer arsenidotetrelate (Li TtAs → Li TtAs + 2Li As) into the lithium poorer arsenidotetrelates and lithium arsenide at moderate temperatures. Impedance spectroscopy shows moderate to good lithium ion conductivity for the lithium arsenidotetrelates.</abstract><cop>England</cop><pmid>38687121</pmid><doi>10.1039/d4dt00664j</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-5309-4301</orcidid><orcidid>https://orcid.org/0000-0001-8653-7439</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1477-9226
ispartof Dalton transactions : an international journal of inorganic chemistry, 2024-07, Vol.53 (27), p.11257-11263
issn 1477-9226
1477-9234
language eng
recordid cdi_crossref_primary_10_1039_D4DT00664J
source Royal Society of Chemistry
title The cubic structure of Li 3 As stabilized by substitution - Li 8 TtAs 4 (Tt = Si, Ge) and Li 14 TtAs 6 (Tt = Si, Ge, Sn) and their lithium ion conductivity
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T05%3A57%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20cubic%20structure%20of%20Li%203%20As%20stabilized%20by%20substitution%20-%20Li%208%20TtAs%204%20(Tt%20=%20Si,%20Ge)%20and%20Li%2014%20TtAs%206%20(Tt%20=%20Si,%20Ge,%20Sn)%20and%20their%20lithium%20ion%20conductivity&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Schmid,%20Martin&rft.date=2024-07-09&rft.volume=53&rft.issue=27&rft.spage=11257&rft.epage=11263&rft.pages=11257-11263&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/d4dt00664j&rft_dat=%3Cpubmed_cross%3E38687121%3C/pubmed_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c581-77349e103b5113a921af537100f7187476c39d6aade0d6211706e3d2082539913%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/38687121&rfr_iscdi=true