Synergistic catalysis of tandem Li/S-1 and Sn-Beta catalysts for the conversion of glucose to fructose and lactic acid at 90 °C in water

• Published in: Green chemistry : an international journal and green chemistry resource : GC 2024-03, Vol.26 (6), p.3165-3169
• Main Authors: Zhang, Yanfei, Li, Wanting, Li, Wenqian, Zhu, Yanfeng, Chen, Longfei, Miao, Gai, Luo, Hu, Chen, Xinqing, Kong, Lingzhao
• Format: Article
• Language: English
• Subjects: Acid production; Aldehydes; Catalysis; Catalysts; Fructose; Glucose; Intermediates; Isomerization; Lactic acid; Lithium; Magnetic resonance spectroscopy; NMR spectroscopy
• ISSN: 1463-9262; 1463-9270
• DOI: 10.1039/d4gc00135d

Efficient simultaneous lactic acid production with fructose isomerization from glucose at 90 °C under atmospheric pressure was demonstrated using a physically mixed Li/S-1 and Sn-Beta catalyst, resulting in a lactic acid yield of 33.1% and a fructose yield of 56.0% for 1 h in water. In situ FTIR and 13 C NMR spectroscopy and the control experiment results revealed the formation of enol intermediates over the Li/S-1 catalyst through a typical alkali-catalyzed reaction in glucose isomerization. In the subsequent tandem catalysis over the Sn-Beta catalyst, strong adsorption between Sn sites and the enol structure efficiently promotes C-C breaking during the retro-aldol reaction process, which was proved by the detailed EXAFS results and DFT calculations. Li/S-1 & Sn-Beta catalysts were exploited to yield fructose (56.0%) and lactic acid (33.1%) from glucose in water at 90 °C under atmospheric pressure.