Structural and luminescence properties of novel Eu 3+ -doped Na 3 Ba 2 LaNb 10 O 30 phosphors with high quantum efficiency and excellent color purity for w-LED applications

• Published in: RSC advances 2024-09, Vol.14 (40), p.29490-29504
• Main Authors: Poria, Kanishk, Bhatia, Sanjana, Kashyap, Rajiv, Kashyap, Vikas, Sihmar, Isha, Deopa, Nisha, Shahi, Jangvir Singh
• Format: Article
• Language: English
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d4ra05026f

In this study, we report the successful synthesis and thorough characterization of Eu -doped Na Ba LaNb O phosphors, targeting their application in white-light-emitting diodes (w-LEDs). The phosphors were synthesized using a high-temperature solid-state method, ensuring robust incorporation of Eu ions into the host lattice. Comprehensive analyses were performed, including X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray (EDX) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and Raman spectroscopy, confirming the phase purity, crystallinity, morphology, and elemental composition of the phosphors. We have also studied the electronic structure using diffuse reflectance spectroscopy (DRS). Photoluminescence studies revealed strong red emissions under near-ultraviolet light excitation, with the optimal Eu doping concentration identified to be 9 mol%. Quantum-yield measurements demonstrated high luminescence efficiency, while chromaticity coordinates indicated excellent color purity suitable for w-LED applications. These findings contribute significantly to the advancement of phosphor materials for solid-state lighting, suggesting promising prospects for their integration into commercial LED devices.