Axially asymmetric metal alkyls. Part 3. Chemical, electrochemical, and structural studies of Group 5A d 0,1,2 metallepines [M{(2-CH 2 C 6 H 4 ) 2 }(η-C 5 H 5 ) 2 ] z (M = Nb or Ta; z=1–, 0, or 1+); synthesis of [Nb{2-CH 2 (C 6 H 4 ) 2 Me-2′}X(η-C 5 H 5 ) 2 ](X = Cl or CO) and [{(η-C 5 H 5 ) 2 ClV} 2 {(2-CH 2 C 6 H 4 ) 2 }], and electrochemistry of [M(CH 2 Ph) 2 –n Cl n (η-C 5 H 5 ) 2 ](n= 0, M = Nb, or Ta; n= 1, M = V)

• Published in: Journal of the Chemical Society. Dalton transactions 1985 (9), p.1747-1759
• Main Authors: Bailey, Stuart I., Engelhardt, Lutz M., Leung, Wing-Por, Raston, Colin L., Ritchie, Ian M., White, Allan H.
• Format: Article
• Language: English
• ISSN: 0300-9246; 1364-5447
• DOI: 10.1039/DT9850001747