Sterically controlled naphthalene homo-oligoamides with novel structural architectures

Herein we report novel naphthalene homo-oligoamides, derived from 4-amino-3-methoxy-naphthalene-2-carboxylic acid and 4-amino-1-methoxy-naphthalene-2-carboxylic acid as monomer building blocks, that display an anti-periplanar arrangement of the naphthyl rings, primarily induced by steric interaction...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2009-01, Vol.7 (11), p.2458
Main Authors: Prabhakaran, Panchami, Puranik, Vedavati G, Chandran, Jima N, Rajamohanan, P R, Hofmann, Hans-Jörg, Sanjayan, Gangadhar J
Format: Article
Language:English
Subjects:
1-Naphthylamine - analogs & derivatives
1-Naphthylamine - chemical synthesis
1-Naphthylamine - chemistry
Amides - chemical synthesis
Amides - chemistry
Crystallography, X-Ray
Dimerization
Magnetic Resonance Spectroscopy
Models, Molecular
Naphthalenes - chemical synthesis
Naphthalenes - chemistry
Quantum Theory
Stereoisomerism
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Summary:Herein we report novel naphthalene homo-oligoamides, derived from 4-amino-3-methoxy-naphthalene-2-carboxylic acid and 4-amino-1-methoxy-naphthalene-2-carboxylic acid as monomer building blocks, that display an anti-periplanar arrangement of the naphthyl rings, primarily induced by steric interactions between adjacent groups and functionalities.
ISSN:1477-0520
1477-0539
DOI:10.1039/b822076j