A new one-pot hydroformylation/Strecker synthesis as a versatile synthetic tool for polyfunctional compounds and functionalization of dendrimers

A versatile and high yielding one-pot hydroformylation/Strecker synthesis is reported for the synthesis of various alpha-aminonitriles. This methodology allows functionalization of dendrimers (e.g. polyamines 4-7) and hyper branched polymers (e.g. polyallyl glycerol 12) to give corresponding dendrit...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2009-01, Vol.7 (19), p.4000
Main Authors: Subhani, Muhammad Afzal, Müller, Kai-Sven, Koç, Fikret, Eilbracht, Peter
Format: Article
Language:English
Subjects:
Alkenes - chemistry
Dendrimers - chemical synthesis
Dendrimers - chemistry
Hydrogen Cyanide - chemistry
Nitriles - chemistry
Polyamines - chemistry
Stereoisomerism
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Summary:A versatile and high yielding one-pot hydroformylation/Strecker synthesis is reported for the synthesis of various alpha-aminonitriles. This methodology allows functionalization of dendrimers (e.g. polyamines 4-7) and hyper branched polymers (e.g. polyallyl glycerol 12) to give corresponding dendritic structures with alpha-aminonitriles and/or amino acids in the outer shell in good to excellent yields.
ISSN:1477-0520
1477-0539
DOI:10.1039/b907787a