Cyclohexane selective oxidation over metal-organic frameworks of MIL-101 family: superior catalytic activity and selectivity

Mesoporous metal-organic frameworks Cr- and Fe-MIL-101 are highly efficient, true heterogeneous and recyclable catalysts for solvent-free selective oxidation of cyclohexane with molecular oxygen and/or tert-butyl hydroperoxide under mild conditions.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (54), p.6812
Main Authors: Maksimchuk, Nataliya V, Kovalenko, Konstantin A, Fedin, Vladimir P, Kholdeeva, Oxana A
Format: Article
Language:English
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Description
Summary:Mesoporous metal-organic frameworks Cr- and Fe-MIL-101 are highly efficient, true heterogeneous and recyclable catalysts for solvent-free selective oxidation of cyclohexane with molecular oxygen and/or tert-butyl hydroperoxide under mild conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc31877f