Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

The applicability of HKUST-1 for the degradation of sulfur mustard and sarin simulants was studied with and without coadsorbed water. Degradation was found to be via hydrolysis and dependent on the nucleophilic substitution reaction, vapour pressure and molecular diameter of the toxicants.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2012-10, Vol.41 (40), p.12346
Main Authors: Roy, Anuradha, Srivastava, Avanish K, Singh, Beer, Shah, Dilip, Mahato, Timir Haran, Srivastava, Anchal
Format: Article
Language:English
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Summary:The applicability of HKUST-1 for the degradation of sulfur mustard and sarin simulants was studied with and without coadsorbed water. Degradation was found to be via hydrolysis and dependent on the nucleophilic substitution reaction, vapour pressure and molecular diameter of the toxicants.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt31888a