Lanthanide based tuning of luminescence in MOFs and dense frameworks - from mono- and multimetal systems to sensors and films

This feature article focuses on tuning options of photoluminescence properties of lanthanide containing Metal-Organic Frameworks (MOFs) and Dense Frameworks by selection of an appropriate set of metal ions together with suitable ligands. In addition to lanthanide-only systems, frameworks with main g...

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Published in:Chemical communications (Cambridge, England) England), 2014-07, Vol.5 (6), p.893-818
Main Authors: Meyer, L. V, Schönfeld, F, Müller-Buschbaum, K
Format: Article
Language:English
Subjects:
Lanthanides
Ligands
Luminescence
Metal-organic frameworks
Sensors
Thin films
Transition metals
Tuning
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description This feature article focuses on tuning options of photoluminescence properties of lanthanide containing Metal-Organic Frameworks (MOFs) and Dense Frameworks by selection of an appropriate set of metal ions together with suitable ligands. In addition to lanthanide-only systems, frameworks with main group and transition metal ions that are heterometallic or co-doped with variable lanthanide content offer excellent tuning options for luminescence. The MOF feature porosity enables further applications such as sensors for a large number of chemical analytes by selective influences on the luminescence upon contact. The application of functional thin films marks the most recent development of this amazingly growing field, involving processing and structuring. This Feature Article illustrates recent developments of luminescent MOFs, Ln-based luminescence tuning in multi-metal systems, luminescence sensing, and thin films.
doi_str_mv 10.1039/c4cc00848k
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Lanthanides
Ligands
Luminescence
Metal-organic frameworks
Sensors
Thin films
Transition metals
Tuning
title Lanthanide based tuning of luminescence in MOFs and dense frameworks - from mono- and multimetal systems to sensors and films
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