Study on Palladium(II)-Catalyzed Mono-1-alkenylation of 9H-Carbazoles

Abstract A general and efficient method is reported for the direct mono-1-alkenylation of 9 H -carbazole molecules with divalent palladium as a catalyst and an N -(2-pyridyl)sulfanyl directing group. This method also provides an efficient synthetic route for the synthesis of cross-dialkenylated carb...

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Bibliographic Details
Published in:Synlett 2021-05, Vol.32 (8), p.800-804
Main Authors: Guo, Dongdong, Li, Bin, Gao, Wenmei, Zhang, Wuxia, Wang, Yongqiang, Zhao, Jinzhong
Format: Article
Language:English
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Summary:Abstract A general and efficient method is reported for the direct mono-1-alkenylation of 9 H -carbazole molecules with divalent palladium as a catalyst and an N -(2-pyridyl)sulfanyl directing group. This method also provides an efficient synthetic route for the synthesis of cross-dialkenylated carbazoles.
ISSN:0936-5214
1437-2096
DOI:10.1055/a-1387-5435