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A Sydnone-Based Route to Indazolo[2,3-a]quinoxaline Derivatives

Abstract A new synthetic route to indazolo[2,3- a ]quinoxaline derivatives is described. The strategy is based on the 1,3-dipolar cycloaddition of arynes to quinoxaline–sydnone derivatives as a key step. The polyaromatic sydnones were prepared through a copper-promoted intramolecular cyclization of...

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Bibliographic Details
Published in:Synlett 2022-05, Vol.33 (8), p.791-794
Main Authors: Louis, Manon, Talbot, Alex, Lamaa, Diana, Sallustrau, Antoine, Audisio, Davide, Taran, Frédéric
Format: Article
Language:English
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Summary:Abstract A new synthetic route to indazolo[2,3- a ]quinoxaline derivatives is described. The strategy is based on the 1,3-dipolar cycloaddition of arynes to quinoxaline–sydnone derivatives as a key step. The polyaromatic sydnones were prepared through a copper-promoted intramolecular cyclization of the C-4 position of sydnones on imines.
ISSN:0936-5214
1437-2096
DOI:10.1055/a-1774-7618