Radical Conjugated Addition: Addition of Dialkyl Phosphonodifluoromethyl Radical onto Unsaturated Ketones

Abstract The free radical addition of phosphonodifluoromethyl radical is reported from iodophosphonate and sodium dithionite, triethylborane, or dilauroyl peroxide as initiator. Triethylborane promoted the radical conjugated addition onto enones.

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Bibliographic Details
Published in:Synlett 2009-04, Vol.2009 (6), p.981-985
Main Authors: Sène, Aboubacary, Diab, Sonia, Hienzsch, Antje, Cahard, Dominique, Lequeux, Thierry
Format: Article
Language:English
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Summary:Abstract The free radical addition of phosphonodifluoromethyl radical is reported from iodophosphonate and sodium dithionite, triethylborane, or dilauroyl peroxide as initiator. Triethylborane promoted the radical conjugated addition onto enones.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0028-1088207