Palladium-Catalyzed Heck-Type Coupling of Allyl Esters: β-Hydride versus β-Acetoxy Elimination

Abstract This account presents recent progress in palladium-­catalyzed Heck-type reactions of allyl esters with aryl halides, arylmetallic reagents, or arenes. Many improvements have been achieved to control the regioselectivity of β-hydride or β-acetoxy elimination. 1 Introduction 2 Palladium-Catal...

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Bibliographic Details
Published in:Synlett 2010-07, Vol.2010 (11), p.1577-1588
Main Authors: Pan, Delin, Jiao, Ning
Format: Article
Language:English
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Summary:Abstract This account presents recent progress in palladium-­catalyzed Heck-type reactions of allyl esters with aryl halides, arylmetallic reagents, or arenes. Many improvements have been achieved to control the regioselectivity of β-hydride or β-acetoxy elimination. 1 Introduction 2 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Aryl Halides 3 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Organometallic Reagents 4 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Arenes via Aromatic C-H Activation 5 Other Transition Metal Catalyzed Heck-Type Reactions of Allyl Esters 6 Conclusion
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0030-1258083