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Recent Developments in Asymmetric Catalysis in the Presence of Chiral Gold Complexes
Abstract Catalytic asymmetric gold-catalyzed reactions provide versatile routes to enantiomerically enriched carbo- and heterocycles. This review summarizes the recent work on the development of novel catalytic systems combining gold and a chiral ligand. 1 Introduction 2 Gold-Catalyzed Activation of...
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Published in: | Synthesis (Stuttgart) 2011-05, Vol.2011 (10), p.1501-1514 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that cite this one |
Online Access: | Get full text |
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Summary: | Abstract
Catalytic asymmetric gold-catalyzed reactions provide versatile
routes to enantiomerically enriched carbo- and heterocycles. This
review summarizes the recent work on the development of novel catalytic
systems combining gold and a chiral ligand.
1 Introduction
2 Gold-Catalyzed Activation of Carbonyl and Imine-Type Bonds
3 Gold-Catalyzed Activation of Alkenes
3.1 Hydrogenation Reactions
3.2 Nucleophilic Additions to Alkenes
4 Gold-Catalyzed Activation of Allenes
4.1 In the Presence of a Chiral Gold Complex
4.1.1 Oxygen Nucleophiles
4.1.2 Nitrogen Nucleophiles
4.1.3 Carbon Nucleophiles
4.2 In the Presence of a Chiral Silver Salt
5 Gold-Catalyzed Activation of Alkynes
5.1 Rearrangement of Propargylic Esters
5.2 Desymmetrization Reactions
5.3 Cycloisomerization of Enynes
5.3.1 In the Absence of an External Nucleophile
5.3.2 In the Presence of a Nucleophile: Domino Processes
5.3.2.1 Oxygen and Nitrogen Nucleophiles
5.3.2.2 Carbon Nucleophiles
6 Conclusion |
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ISSN: | 0039-7881 1437-210X |
DOI: | 10.1055/s-0030-1258465 |