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Recent Developments in Asymmetric Catalysis in the Presence of Chiral Gold Complexes

Abstract Catalytic asymmetric gold-catalyzed reactions provide versatile routes to enantiomerically enriched carbo- and heterocycles. This review summarizes the recent work on the development of novel catalytic systems combining gold and a chiral ligand. 1 Introduction 2 Gold-Catalyzed Activation of...

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Published in:Synthesis (Stuttgart) 2011-05, Vol.2011 (10), p.1501-1514
Main Authors: Pradal, Alexandre, Toullec, Patrick Y., Michelet, Véronique
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Language:English
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container_title Synthesis (Stuttgart)
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creator Pradal, Alexandre
Toullec, Patrick Y.
Michelet, Véronique
description Abstract Catalytic asymmetric gold-catalyzed reactions provide versatile routes to enantiomerically enriched carbo- and heterocycles. This review summarizes the recent work on the development of novel catalytic systems combining gold and a chiral ligand. 1 Introduction 2 Gold-Catalyzed Activation of Carbonyl and Imine-Type Bonds 3 Gold-Catalyzed Activation of Alkenes 3.1 Hydrogenation Reactions 3.2 Nucleophilic Additions to Alkenes 4 Gold-Catalyzed Activation of Allenes 4.1 In the Presence of a Chiral Gold Complex 4.1.1 Oxygen Nucleophiles 4.1.2 Nitrogen Nucleophiles 4.1.3 Carbon Nucleophiles 4.2 In the Presence of a Chiral Silver Salt 5 Gold-Catalyzed Activation of Alkynes 5.1 Rearrangement of Propargylic Esters 5.2 Desymmetrization Reactions 5.3 Cycloisomerization of Enynes 5.3.1 In the Absence of an External Nucleophile 5.3.2 In the Presence of a Nucleophile: Domino Processes 5.3.2.1 Oxygen and Nitrogen Nucleophiles 5.3.2.2 Carbon Nucleophiles 6 Conclusion
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subjects Catalysis
Catalysts: preparations and properties
Chemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
review
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title Recent Developments in Asymmetric Catalysis in the Presence of Chiral Gold Complexes
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