Fe(OTf)3-Catalyzed Reaction of Benzylic Acetates with Organosilicon Compounds

Abstract Fe(OTf) 3 -catalyzed reaction of benzylic acetates with allyltrimethylsilane, azidotrimethylsilane, and cyanotrimethylsilane afforded the corresponding allylated, azido, and cyano products in high yields. 2-Trimethylsilyl-substituted benzofuran and indole worked well to furnish the benzyl-s...

Full description

Saved in:
Bibliographic Details
Published in:Synlett 2011-02, Vol.2011 (3), p.415-419
Main Authors: Chan, Li Yan, Kim, Sundae, Chung, Wan Ting, Long, Chong, Kim, Sunggak
Format: Article
Language:English
Subjects:
Catalysis
Catalysts: preparations and properties
Chemistry
Exact sciences and technology
General and physical chemistry
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Heterocyclic compounds with only one n hetero atom and condensed derivatives
Kinetics and mechanisms
letter
Organic chemistry
Preparations and properties
Reactivity and mechanisms
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Abstract Fe(OTf) 3 -catalyzed reaction of benzylic acetates with allyltrimethylsilane, azidotrimethylsilane, and cyanotrimethylsilane afforded the corresponding allylated, azido, and cyano products in high yields. 2-Trimethylsilyl-substituted benzofuran and indole worked well to furnish the benzyl-substituted benzofuran and indoles.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0030-1259313