Rhodium-Catalyzed Carbene-Transfer Reactions via Thienylcarbene Complexes Generated from Thiocarbamoyl-ene-yne Compounds

Abstract Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide ef...

Full description

Saved in:
Bibliographic Details
Published in:Synlett 2011-03, Vol.2011 (5), p.655-658
Main Authors: Tsuneishi, Asuka, Okamoto, Kazuhiro, Ikeda, Yuji, Murai, Masahito, Miki, Koji, Ohe, Kouichi
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Free radicals chemistry
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
letter
Organic chemistry
Preparations and properties
Reactivity and mechanisms
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Abstract Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide efficient synthetic methods for thiophene-containing complex molecules.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0030-1259559