Hypervalent Iodine(III)-LiX Combination in Fluoroalcohol Solvent for Aromatic Halogenation of Electron-Rich Arenecarboxylic Acids

Abstract The novel reagent system, PhI(OAc) 2 -LiX combination in fluoroalcohol solvents, was found to be effective for halodecarboxylation of electron-rich arenecarboxylic acids. The method provided an efficient route to halogenated phenol ether derivatives.

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Bibliographic Details
Published in:Synlett 2011-07, Vol.2011 (11), p.1563-1566
Main Authors: Hamamoto, Hiromi, Hattori, Sho, Takemaru, Kaori, Miki, Yasuyoshi
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
letter
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
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Description
Summary:Abstract The novel reagent system, PhI(OAc) 2 -LiX combination in fluoroalcohol solvents, was found to be effective for halodecarboxylation of electron-rich arenecarboxylic acids. The method provided an efficient route to halogenated phenol ether derivatives.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0030-1260791