Hypervalent Iodine(III)-LiX Combination in Fluoroalcohol Solvent for Aromatic Halogenation of Electron-Rich Arenecarboxylic Acids

Abstract The novel reagent system, PhI(OAc) 2 -LiX combination in fluoroalcohol solvents, was found to be effective for halodecarboxylation of electron-rich arenecarboxylic acids. The method provided an efficient route to halogenated phenol ether derivatives.

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Published in:Synlett 2011-07, Vol.2011 (11), p.1563-1566
Main Authors: Hamamoto, Hiromi, Hattori, Sho, Takemaru, Kaori, Miki, Yasuyoshi
Format: Article
Language:English
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Chemistry
Exact sciences and technology
letter
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
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container_issue 11
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container_title Synlett
container_volume 2011
creator Hamamoto, Hiromi
Hattori, Sho
Takemaru, Kaori
Miki, Yasuyoshi
description Abstract The novel reagent system, PhI(OAc) 2 -LiX combination in fluoroalcohol solvents, was found to be effective for halodecarboxylation of electron-rich arenecarboxylic acids. The method provided an efficient route to halogenated phenol ether derivatives.
doi_str_mv 10.1055/s-0030-1260791
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subjects Chemistry
Exact sciences and technology
letter
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
title Hypervalent Iodine(III)-LiX Combination in Fluoroalcohol Solvent for Aromatic Halogenation of Electron-Rich Arenecarboxylic Acids
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