Mechanistic Insights into Palladium Leaching in Novel Pd/C-Catalyzed Boron-Heck Reaction of Arylboronic Acid

Abstract For the first time, Pd/C has been used for the Boron-Heck reaction, and the detailed mechanistic aspects of the reaction have been proven experimentally by a leaching test as well as by cyclic voltammetry studies. The results indicate that palladium leaching as a Pd(II) species, by oxidativ...

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Bibliographic Details
Published in:Synlett 2013-02, Vol.24 (3), p.347-350
Main Authors: Dighe, Mahesh G., Lonkar, Sachin L., Degani, Mariam S.
Format: Article
Language:English
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Summary:Abstract For the first time, Pd/C has been used for the Boron-Heck reaction, and the detailed mechanistic aspects of the reaction have been proven experimentally by a leaching test as well as by cyclic voltammetry studies. The results indicate that palladium leaching as a Pd(II) species, by oxidative addition of the arylboronic acid, is responsible for the reaction.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0032-1318110