Amination of Arylboronic Compounds via the Copper-Catalyzed Addition of Arylboronic Esters to Azodicarboxylates

Abstract Arylboronic esters add to di- tert -butyl azodicarboxylate under mild reaction conditions (at room temperature) to afford aryl-substituted­ hydrazine derivatives in good yields. The reaction tolerates a wide variety of functional groups.

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Bibliographic Details
Published in:Synthesis (Stuttgart) 2015-12, Vol.47 (23), p.3746-3750
Main Authors: Uemura, Takeshi, Yamaguchi, Mao, Chatani, Naoto
Format: Article
Language:English
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Description
Summary:Abstract Arylboronic esters add to di- tert -butyl azodicarboxylate under mild reaction conditions (at room temperature) to afford aryl-substituted­ hydrazine derivatives in good yields. The reaction tolerates a wide variety of functional groups.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0035-1560468