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One-Pot Synthesis of Novel Highly Functionalized Furan-Based Polyphenolics

Abstract Novel, highly functionalized furan-based polyphenolics were prepared. The employed methodology involves a one-pot 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) catalyzed 1,4-conjugate addition of 1,3-dicarbonyl compounds on 3-bromochromones, furan heterocyclization, and chromanone ring opening.

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Bibliographic Details
Published in:Synlett 2015-12, Vol.26 (19), p.2724-2729
Main Authors: Sousa, Joana L. C., Talhi, Oualid, Rocha, Djenisa H. A., Pinto, Diana C. G. A., Almeida Paz, Filipe A., Bachari, Khaldoun, Kirsch, Gilbert, Silva, Artur M. S.
Format: Article
Language:English
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Summary:Abstract Novel, highly functionalized furan-based polyphenolics were prepared. The employed methodology involves a one-pot 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) catalyzed 1,4-conjugate addition of 1,3-dicarbonyl compounds on 3-bromochromones, furan heterocyclization, and chromanone ring opening.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0035-1560580