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Green Organocatalytic Oxidation of Sulfides to Sulfoxides and Sulfones

Abstract A highly efficient synthetic methodology towards the selective synthesis of sulfoxides and sulfones is reported using a cheap and green organocatalytic method. Starting from sulfides and using 2,2,2-trifluoroacetophenone as the organocatalyst and H 2 O 2 as the oxidant, the high-yielding pr...

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Bibliographic Details
Published in:Synthesis (Stuttgart) 2016-09, Vol.49 (4), p.917-924
Main Authors: Voutyritsa, Errika, Triandafillidi, Ierasia, Kokotos, Christoforos G.
Format: Article
Language:English
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Summary:Abstract A highly efficient synthetic methodology towards the selective synthesis of sulfoxides and sulfones is reported using a cheap and green organocatalytic method. Starting from sulfides and using 2,2,2-trifluoroacetophenone as the organocatalyst and H 2 O 2 as the oxidant, the high-yielding preparation of sulfoxides or sulfones is described, being dependent on the reaction conditions.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0036-1588315