Nickel-Catalyzed Reductive Cross-Coupling of Aryl Triflates and Nonaflates with Alkyl Iodides

Abstract A nickel-catalyzed cross-electrophile coupling of aryl triflates and nonaflates with alkyl iodides using manganese(0) as a reductant is described. The method is applicable to the reductive alkylation of various aryl sulfonates, including o -borylaryl triflate, which enabled efficient constr...

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Bibliographic Details
Published in:Synthesis (Stuttgart) 2017-08, Vol.49 (16), p.3590-3601
Main Authors: Sumida, Yuto, Sumida, Tomoe, Hosoya, Takamitsu
Format: Article
Language:English
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special topic
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Summary:Abstract A nickel-catalyzed cross-electrophile coupling of aryl triflates and nonaflates with alkyl iodides using manganese(0) as a reductant is described. The method is applicable to the reductive alkylation of various aryl sulfonates, including o -borylaryl triflate, which enabled efficient construction of diverse alkylated arenes under mild conditions.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0036-1588464