Synthesis of Allylbenzene Derivatives through sp3 C–H Bond Functionalization of Toluene Derivatives

Abstract An sp 3 C–H bond-transformation reaction of toluene substrates to afford the corresponding allylbenzene derivatives is described. Optimum conditions were identified as involving the use of tetrabutylammonium iodide and tert -butyl hydroperoxide at 80 °C.

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Bibliographic Details
Published in:Synlett 2017-08, Vol.28 (13), p.1646-1648
Main Authors: Shahsavari, Fatemeh, Abbasi, Alireza, Ghazanfarpour-Darjani, Majid, Ghafelebashi, Seyed Mehdi, Daftari-Besheli, Majid
Format: Article
Language:English
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Summary:Abstract An sp 3 C–H bond-transformation reaction of toluene substrates to afford the corresponding allylbenzene derivatives is described. Optimum conditions were identified as involving the use of tetrabutylammonium iodide and tert -butyl hydroperoxide at 80 °C.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0036-1588793