Synthesis of Allylbenzene Derivatives through sp3 C–H Bond Functionalization of Toluene Derivatives

Abstract An sp 3 C–H bond-transformation reaction of toluene substrates to afford the corresponding allylbenzene derivatives is described. Optimum conditions were identified as involving the use of tetrabutylammonium iodide and tert -butyl hydroperoxide at 80 °C.

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Published in:Synlett 2017-08, Vol.28 (13), p.1646-1648
Main Authors: Shahsavari, Fatemeh, Abbasi, Alireza, Ghazanfarpour-Darjani, Majid, Ghafelebashi, Seyed Mehdi, Daftari-Besheli, Majid
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container_end_page 1648
container_issue 13
container_start_page 1646
container_title Synlett
container_volume 28
creator Shahsavari, Fatemeh
Abbasi, Alireza
Ghazanfarpour-Darjani, Majid
Ghafelebashi, Seyed Mehdi
Daftari-Besheli, Majid
description Abstract An sp 3 C–H bond-transformation reaction of toluene substrates to afford the corresponding allylbenzene derivatives is described. Optimum conditions were identified as involving the use of tetrabutylammonium iodide and tert -butyl hydroperoxide at 80 °C.
doi_str_mv 10.1055/s-0036-1588793
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title Synthesis of Allylbenzene Derivatives through sp3 C–H Bond Functionalization of Toluene Derivatives
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