Phosphorus-Substituted Azulenes Accessed via Direct Hafner Reaction of a Phosphino Cyclopentadienide

Abstract The Hafner azulene synthesis may be applied to the direct synthesis of phosphorus-substituted azulenes, when a phosphinocyclopentadienide is used as one of the reactants. The azulenyl phosphines produced in this fashion are preferentially isolated as the corresponding phosphine oxides or ph...

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Published in:Synlett 2017-05, Vol.28 (8), p.973-975
Main Authors: Gee, Anthony P., Cosham, Samuel D., Johnson, Andrew L., Lewis, Simon E.
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creator Gee, Anthony P.
Cosham, Samuel D.
Johnson, Andrew L.
Lewis, Simon E.
description Abstract The Hafner azulene synthesis may be applied to the direct synthesis of phosphorus-substituted azulenes, when a phosphinocyclopentadienide is used as one of the reactants. The azulenyl phosphines produced in this fashion are preferentially isolated as the corresponding phosphine oxides or phosphine borane adducts.
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title Phosphorus-Substituted Azulenes Accessed via Direct Hafner Reaction of a Phosphino Cyclopentadienide
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