Experimental and Theoretical Study of the Reaction Kinetics of 2,5-Dimethylterephthalonitrile Bromination Compared to 1,4-Dimethylbenzene Bromination

Abstract Experimental and theoretical studies showed the differences observed in the benzylic tetrabromination reactions in 2,5-dimethylterephthalonitrile compared to 1,4-dimethylbenzene. It was observed that the compound containing the nitrile substituent underwent a slower bromination reaction, wi...

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Published in:Synthesis (Stuttgart) 2018-03, Vol.50 (6), p.1259-1263
Main Authors: Villalba, Cibeli M. A., de C Rozada, Thiago, dos Santos, Fábio S., Scorsin, Leandro, Garcia, Jarem R., Fiorin, Barbara C.
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container_issue 6
container_start_page 1259
container_title Synthesis (Stuttgart)
container_volume 50
creator Villalba, Cibeli M. A.
de C Rozada, Thiago
dos Santos, Fábio S.
Scorsin, Leandro
Garcia, Jarem R.
Fiorin, Barbara C.
description Abstract Experimental and theoretical studies showed the differences observed in the benzylic tetrabromination reactions in 2,5-dimethylterephthalonitrile compared to 1,4-dimethylbenzene. It was observed that the compound containing the nitrile substituent underwent a slower bromination reaction, with the formation of four intermediate compounds, while for the compound without substituents, the reaction was faster and only two intermediate compounds were observed.
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title Experimental and Theoretical Study of the Reaction Kinetics of 2,5-Dimethylterephthalonitrile Bromination Compared to 1,4-Dimethylbenzene Bromination
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