Diene Synthesis by the Reductive Transposition of 1,2-Allenols

Abstract Monoalkyl diazene species are versatile intermediates that have enabled many useful synthetic transformations in complex chemical environments. Herein we report the reductive transposition of 1,2-allenols for the direct synthesis of dienes through an alkene walk process.

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Bibliographic Details
Published in:Synlett 2019-11, Vol.30 (18), p.2073-2076
Main Authors: Rinaolo, Vincent J., Robinson, Emily E., Diagne, Abdallah B., Schaus, Scott E., Thomson, Regan J.
Format: Article
Language:English
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Description
Summary:Abstract Monoalkyl diazene species are versatile intermediates that have enabled many useful synthetic transformations in complex chemical environments. Herein we report the reductive transposition of 1,2-allenols for the direct synthesis of dienes through an alkene walk process.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0039-1690692