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Reductive Cross-Coupling of Vinyl Electrophiles

Abstract The synthesis of alkenes (olefins) is a central subject in the synthetic community. The transition-metal-catalyzed reductive cross-coupling of vinyl electrophiles has emerged as a promising tool to produce alkenes with improved flexibility, structural complexity, and functionality tolerance...

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Bibliographic Details
Published in:Synthesis (Stuttgart) 2020-12, Vol.52 (24), p.3751-3763
Main Authors: Pang, Xiaobo, Peng, Xuejing, Shu, Xing-Zhong
Format: Article
Language:English
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Summary:Abstract The synthesis of alkenes (olefins) is a central subject in the synthetic community. The transition-metal-catalyzed reductive cross-coupling of vinyl electrophiles has emerged as a promising tool to produce alkenes with improved flexibility, structural complexity, and functionality tolerance. In this review, we summarized the progress in this field with respect to cross-electrophile couplings and reductive Heck reactions using vinyl electrophiles. 1 Introduction 2 Cross-Electrophile Coupling of Vinyl Electrophiles 3 Reductive Heck Reaction of Vinyl Electrophiles 4 Summary and Outlook
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0040-1707342